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Sambhu Bhadra,Nikhil K. Singha,Dipak Khastgir 한국물리학회 2009 Current Applied Physics Vol.9 No.3
The preparation of polyaniline (PAni) was carried out by the oxidative emulsion polymerization of aniline and the semi-conducting composites were prepared by mixing it with a polyolefinic thermoplastic elastomer ethylene 1-octene copolymer (EN). Different electrical properties and electromagnetic interference shielding efficiency (EMI SE) of these composites were measured. The results revealed that the incorporation of PAni in EN increases the conductivity, dielectric constant, dielectric loss and EMI SE. These composites exhibit pressure dependent dielectric properties and may act as pressure sensor. There are increase in AC conductivity and decrease in dielectric constant with the increase in applied pressure on composites. A model correlation between EMI SE and AC conductivity at same frequency for the composites having maximum 40% of PAni was obtained through extrapolation and linear regression analysis, which shows that EMI SE has linear relationship with AC conductivity. Because of their semi-conductive behavior these composites can find application as antistatic materials and electromagnetic interference (EMI) shielding material. The preparation of polyaniline (PAni) was carried out by the oxidative emulsion polymerization of aniline and the semi-conducting composites were prepared by mixing it with a polyolefinic thermoplastic elastomer ethylene 1-octene copolymer (EN). Different electrical properties and electromagnetic interference shielding efficiency (EMI SE) of these composites were measured. The results revealed that the incorporation of PAni in EN increases the conductivity, dielectric constant, dielectric loss and EMI SE. These composites exhibit pressure dependent dielectric properties and may act as pressure sensor. There are increase in AC conductivity and decrease in dielectric constant with the increase in applied pressure on composites. A model correlation between EMI SE and AC conductivity at same frequency for the composites having maximum 40% of PAni was obtained through extrapolation and linear regression analysis, which shows that EMI SE has linear relationship with AC conductivity. Because of their semi-conductive behavior these composites can find application as antistatic materials and electromagnetic interference (EMI) shielding material.
Sabyasachi Ghosh,Sayan Ganguly,Poushali Das,Tushar Kanti Das,Madhuparna Bose,Nikhil K. Singha,Amit Kumar Das,Narayan Ch. Das 한국섬유공학회 2019 Fibers and polymers Vol.20 No.6
Conductive filler loading in the polymer matrix is a common practice to transform insulative polymers toconducting composites. In case of textiles, the highly promising approach has been coined by virtue of fabricating withconductive adhesive homogeneous coating. The present fabrication approach has been developed by two-stage wet mixingtechnique including synthesis of silver nanoparticles decorated graphene sheets (rGO/Ag), followed by the preparation ofconducting coating by non-ionic polymer adhesive. The novelty lies in the choice of conductive material and coating strategyto make lightweight and flexible smart electronic fabric. In order to protect the radiation pollution from the immense use ofelectronic devices and gadgets, the coated textiles can be an excellent replacement of other commercially available polymercoatings. The electromagnetic interference (EMI) shielding effectiveness of the prepared coated textile was 27.36 dB in the Xband (8.2-12.4 GHz). Besides this it is worth mentioning that our developed coated fabric was enough conductive to light upa series of 57 LEDs with high intensity. Last but not the least this work also reconnoitres bactericidal feature against E. coli.
Sabyasachi Ghosh,Subhadip Mondal,Sayan Ganguly,Sanjay Remanan,Nikhil Singha,Narayan Ch. Das 한국섬유공학회 2018 Fibers and polymers Vol.19 No.5
Herein, an intelligent cotton fabric was fabricated using a non-ionic surfactant based macro structured carbonaceous coating through the ‘knife-over-roll’ technique. The developed novel fabric was tested as flexible, mechanically robust with prolonged chemical/moisture resistance. Various characterization techniques were thoroughly used to analyze the fabric. The as-prepared fabric shows an outstanding electromagnetic interference (EMI) shielding efficiency (SE) of about 21.5 dB even at the lowest possible coating thickness (0.20 mm) where the highest EMI SE of 30.8 dB is obtained at only 0.30 mm coating thickness over the X-band frequency range (8.2-12.4 GHz), possibly due to the threedimensionally interconnected network structure of conducting carbon particles. The micro-computed tomography disclosed the porous architecture and “void-filler” arrangement within the fabrics. For the betterment of serviceability and practicability of the coated fabric, the water tolerance and contact angle studies were conducted. The relatively high contact angle than pure cotton fabric, and excellent water resistance after coating ensure improved endurance for external or industrial uses. Therefore, this proof-of-construct manifests commercialization of the developed fabric for multipurpose applications in a facile, less-hazardous and economical way.