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Hayam A. Abd El Salam,Mohamed S. Abdel‑Aziz,Eslam Reda El‑Sawy,Elkhabiry Shaban 한국섬유공학회 2023 Fibers and polymers Vol.24 No.8
For conjugating sulfa drug moieties with Schiff’s bases scaffold in the same build through an azo linker to take advantage of the bioactive feature of both motifs, we designed and synthesized a series of bioactive disperse dyes. The target disperse dyes, methyl 2-(E-2-hydroxy-5-((E)-(4-sulfa-derivative) diazenyl)benzylidene) hydrazine-1-carbodithioates 4a–e have been synthesized via the acidic reaction of azo dyes 3a–e with methyl hydrazine carbodithioate. Structures of the synthesized dyes were clarified based on their spectral and elemental analyses. The effectiveness of the dyes was initially tested as an antibacterial toward Staphylococcus aureus ATCC 6538-P and Escherichia coli ATCC 25933. Dyes that were proven to be effective against bacteria have been used as disperse dyes to print polyester fabrics. The color properties of the dyes and their fastness properties counting washing, perspiration, light, rubbing, and sublimation fastness were also examined. The printed polyester fabrics were evaluated for their antibacterial activity via colony-forming unit (CFU) technique. Fabric samples treated with 4c, 4d, and 4b had promising anti-Gram-positive activities against S. aureus. Whereas 4c-, 4d-, and 4b-treated fabrics exhibited moderate anti-Gram-negative activities against the test bacterium E. coli.
DFT and experimental study on adsorption of dyes on activated carbon prepared from apple leaves
Abdel-Aziz Mohamed Helmy,El-Ashtoukhy Elsayed Zakaria,Bassyouni Mohamed,Al-Hossainy Ahmed Farouk,Fawzy Eman M.,Abdel-Hamid Shereen M. S.,Zoromba Mohamed Shafick 한국탄소학회 2021 Carbon Letters Vol.31 No.5
This work reports utilization of apple leaves as a source of activated carbon. Activated carbon from apple leaves is prepared by two diferent methods, thermal activation where AC1 is obtained and chemical activation using H3PO4 and ZnCl2 where AC2 and AC3 are obtained, respectively. XRD analysis revealed that all types of prepared ACs have a semi-crystalline nature with a mean crystallite size of 13, 21.02, and 39.47 nm for AC1, AC2, and AC3, respectively. To identify the most suitable desorption temperature, the exothermic behavior was discovered for the three types of ACs by DSC. The exothermic onset temperatures are 340 °C, 200 °C, 400 °C, or AC1, AC2, and AC3, respectively. The point of zero charge for the three types of ACs is 8.6, 7.3, and 2.5 for AC1, AC2, and AC3, respectively. The BET surface area analysis data demonstrated that mesoporous structure was developed in AC1 and AC2, while a microporous structure was developed in AC3. Quantum chemical calculations for ACs is carried out using Density Functional Theory (DFT). Application of the prepared ACs in adsorption of basic dye C.I. base blue 47 is studied. The maximum removal efciency was 65.1%, 96% and 99% for AC1, AC2, and AC3, respectively under the infuence of diferent operating aspects. Adsorption data are modeled by Langmuir, Freundlich, and Temkin isotherms. The data revealed that adsorption of basic dye C.I. base blue 47 on AC1 follows Langmuir isotherm and adsorption on AC2 and AC3 follows Freundlich isotherm.
Ginger Extract as Green Corrosion Inhibitor for Steel in Sulfide Polluted Salt Water
Fouda, Abd El-Aziz S.,Nazeer, Ahmed Abdel,Ibrahim, Mohamed,Fakih, Mohamed Korean Chemical Society 2013 대한화학회지 Vol.57 No.2
Extract of ginger has been evaluated as a green inhibitor for the corrosion of steel in sulfide polluted NaCl solution using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. Potentiodynamic polarization measurements showed that this extract acts as a mixed type inhibitor but mainly inhibits the cathodic reaction. The inhibition efficiency was found to increase with inhibitor concentration reaching to approximately 83.9% using 250 ppm of ginger. Nyquist plots show a single capacitive loop in uninhibited and inhibited solutions. From EFM the causality factors are very close to theoretical values which indicate that the measured data are of good quality. The adsorption process of the studied extract on steel surface obeys Temkin adsorption isotherm. The results obtained from the different electrochemical techniques were in good agreement which prove the validity of these tools in measurement of corrosion rate. Ginger extract has no effect on Escherichia Coli and can be applied safely on waste water treatment plants.
Fouda, Abd El-Aziz S.,Nazeer, Ahmed Abdel,El-Khateeb, Ayman Y.,Fakih, Mohamed Korean Chemical Society 2014 대한화학회지 Vol.58 No.4
The inhibition effect of cinnamon plant extract as a green corrosion inhibitor for steel in sulfide polluted salt water was studied by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and electrochemical frequency modulation (EFM). The results showed that cinnamon plant extract in sulfide polluted salt water is a good corrosion inhibitor with inhibition efficiency reached to 80% at 250 ppm of the plant extract. The adsorption of cinnamon obeys Temkin adsorption isotherm, and acts as a mixed-type of inhibitor but dominantly as a cathodic inhibitor in sulfide polluted salt water.
Environmentally benign Scouring of Cotton Knits Using Locally Produced Acid Pectinase Enzyme
Nabil A. Ibrahim,Basma M. Eid,Mohamed S. Abdel Aziz,Soha M. Hamdy,Safaa E. AbdAllah 한국섬유공학회 2019 Fibers and polymers Vol.20 No.4
The main task of the present study is to pre-screen selected fungal strain (Fusarium oxysporum M1-EGY) isolatedfrom local agriculture soil and optimize cultivation conditions for an acid pectinase production. Experimental resultsdemonstrated the optimum conditions for achieving the highest enzyme activity (14.80 U/ml) were found to be: incubationperiod (8 days) at pH (5), temperature (30 oC), and shaking rate (150 rpm), apple pectin carbon source (2 %), and ammoniumphosphate as nitrogen source (0.2 gN/l). The positive impacts of utilizing the produced crude acid-pectinase in eco-friendlyscouring of various cotton knits as well as their subsequent bleaching and reactive dyeing have been confirmed. Additionally,the use of local resources for an acid pectinase production would encourage and promote local production of textile enzymesand their potential applications in Egyptian textile sector, taking in consideration efficiency, textile quality, environmental andeconomy concerns.