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      • KCI등재

        SYNTHESIS AND CHARACTERIZATION OF AU NANOPARTICLES/REDUCED GRAPHENE OXIDE NANOCOMPOSITE: A FACILE AND ECO-FRIENDLY APPROACH

        MEILING ZOU,HAN ZHU,PAN WANG,MINGLIANG DU,MING ZHANG,SHIYONG BAO 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2014 NANO Vol.9 No.3

        In this paper, epigallocatechin gallate (EGCG) was used as a green reductant both for thefabrication of soluble reduced graphene oxide (rGO) and the synthesis of Au nanoparticles/rGOnanocomposite. Fourier transform infrared (FTIR) spectra con¯rmed the e±cient removal of theoxygen-containing groups in graphene oxide (GO) through the reduction act of EGCG. Aunanoparticles (AuNPs) were anchored onto the rGO sheets by heating the mixed solution of rGOand chloroauric acid at 65?C using EGCG as reductant. Transmission electron microscopy(TEM), atomic force microscope (AFM) and X-ray photoelectron spectroscopy (XPS) wereemployed to characterize the resulting nanocomposite. Due to the chelating e®ect of polyhydroxyEGCG, AuNPs with diameters of ? 20 – 50 nm were stably decorated onto both sides of the rGOsheets. Because this reduction method avoids the use of toxic reagents, AuNPs/rGO nano-composite would be eco-friendly, and it might be useful not only for electronic devices but also forbiocompatible materials in the future applications.

      • KCI등재

        Bridgman growth, luminescence and energy transfer studies of Tm3+ or/and Dy3+ co-doped Bi4Si3O12 crystal phosphor

        Bobo Yang,Jiayue Xu,Jun Zou,Yan Zhang,Tian Tian,Yaoqing Chu,Meiling Wang 한양대학교 세라믹연구소 2016 Journal of Ceramic Processing Research Vol.17 No.6

        Tm3+, Dy3+ and Tm3+/Dy3+ co-doped bismuth silicate (Bi4Si3O12, BSO) crystals were successfully grown by the modified verticalBridgeman method. The crystals have about 80% transmittance in the range from 320 nm to 650 nm except several obviouscharacteristic absorption peaks corresponding to transitions of 4f electrons of Tm3+ and Dy3+. The luminescence properties forwhite light emitting diode (w-LED) were investigated. Energy transfer from the Bi3+ ions to the Tm3+ and Dy3+ ions in Tm3+or/and Dy3+ co-doped Bi4Si3O12 crystal has been established by photoluminescence investigation upon UV excitation. Whenexcited by a proper UV-light, Tm3+ doped BSO crystal shows blue emission band centered at 460 nm ascribed to Tm3+ (1D2→ 3F4), Dy3+ doped BSO crystal shows blue band at 480 nm (4F9/2→ 6H15/2), yellow band at 574 nm (4F9/2→ 6H13/2) and red bandat 662 nm (4F9/2→ 6H11/2) of Dy3+ ions. A white light with chromaticity coordinate of x = 0.3298, y = 0.2905 by excitation of357 nm is achieved from Tm3+/Dy3+ co-doped Bi4Si3O12 crystal. These results indicate that Tm3+/Dy3+ co-doped Bi4Si3O12 as awhite emitting crystal has a potential application in white-LED.

      • KCI등재

        TEMPLATE STRATEGY FOR THE SYNTHESIS OF Cu2O-Pt HIERARCHICAL HETEROSTRUCTURES FOR THE DEGRADATION OF METHYLENE BLUE

        SHIYONG BAO,HAN ZHU,PAN WANG,MEILING ZOU,MINGLIANG DU,MING ZHANG 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2013 NANO Vol.8 No.6

        A facile and green route was introduced to synthesize Pt nanoparticles (PtNPs) immobilized on Cu2O octahedrons to form Cu2O–Pt hierarchical heterostructure. Transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), high resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) were employed to study their morphology, chemical and crystallographic properties of the Cu2O–Pt hierarchical heterostructure. These novel Cu2O–Pt hierarchical heterostructures show fascinating degradations of methylene blue (MB), due to the suppressed electron/hole recombination phenomena and the efficient ability to capture the light.

      • KCI등재

        Removal of aqueous vanadium(V) by green synthesized iron nanoparticles supported on corn straw biochar

        Kun Rong,Xueping Li,Qian Yang,Ruimin Li,Zaiwang Zhang,Meiling Zou,Huanqiang Zheng,Juanjuan Liu 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.120 No.-

        Iron nanoparticles supported on corn straw biochar (PE-FeNPs@BC) were used to remove V(V). This materialwas prepared by using Yali pear peel extract-supported iron nanoparticles (PE-FeNPs) as the functionalbody and corn straw biochar (BC) as the support. The synthesis conditions such as Fe/C massratio and synthesis temperature were optimized. The material was characterized by SEM-EDS, FTIR,XRD, and XPS. The results showed that particle agglomeration was reduced, and the dispersion wasimproved after PE-FeNPs were supported on BC. The removal effect was better in the pH range of 2–6,and the removal efficiency was the highest at pH 3.7. At 25 ℃ and pH 3.7, the maximum adsorptioncapacity qm of V(V) was 362.7 mg/g, and 95.1 % of 90 mg/L V(V) was removed. The coexisting NaCl orNaNO3 had a weaker effect on the removal of V(V). The adsorption reactions followed the pseudosecond-order model and Langmuir model, and chemical adsorption was the dominant process. The mainreaction mechanism of PE-FeNPs@BC with V(V) was as follows: adsorbed V5+ was reduced to V4+ by Fe0and Fe2+ and then removed by co-precipitation in the forms of xFe2O3yV2O5zH2O and VO2H2O. Thisstudy promotes the reuse of waste pear peel and can provide an environmentally friendly method forremoving V(V) pollution.

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