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Controlled synthesis and luminescence properties of doped NaLa(WO4)2 microstructures
Yunhua Han,Yan Wang,Shaohua Huang,Fan-Long Jin,Shili Gai,Na Niu,Liuzhen Wang,Piaoping Yang 한국공업화학회 2016 Journal of Industrial and Engineering Chemistry Vol.34 No.-
In this work, well-defined NaLa(WO4)2microstructures were prepared by a facile hydrothermal processin the presence of oleylamine and oleic acid as a mixed surfactant. The phase, morphology, size andluminescence properties were well characterized by means of X-ray diffraction (XRD), scanning electronmicroscopy (SEM), transmission electron microscopy (TEM), photoluminescence (PL) spectra, and decaytime, respectively. The results reveal that the morphology and size of the as-synthesized samples can betuned by altering the reaction time and the amounts of oleic acid. A possible formation mechanism oftetragonal NaLa(WO4)2 is proposed on the basis of oleic acid amount-dependent experiments. Uponultraviolet (UV) excitation, NaLa(WO4)2:Eu3+ and NaLa(WO4)2:Tb3+ exhibit the characteristic downconversionemissions of Eu3+ and Tb3+. Yb3+/Er3+ and Yb3+/Tm3+ co-doped NaLa(WO4)2 samples showstrong green (Er3+, 4S3/2, 2H11/2!4I15/2) and blue (Tm3+, 1G4!3H6) up-conversion emission under980 nm laser diode excitation. Upconversion emission mechanisms of NaLa(WO4)2:Ln (Ln = Yb/Er, Yb/Tm) are also presented based on the emission spectra and the plot of luminescence intensity to pumppower. It should be noted that the intensity of the upconversion emissions can be dramatically enhancedcompared with sodium free tungstates, which can be attributed to the charge compensation and meansthe introduction of Na+ ions in WO42 causes less distortion in the crystal structure.
Controlled synthesis of transition metal/conducting polymer nanocomposites
Liu, Zhen,Liu, Yang,Zhang, Lin,Poyraz, Selcuk,Lu, Ning,Kim, Moon,Smith, James,Wang, Xiaolong,Yu, Yajiao,Zhang, Xinyu IOP Pub 2012 Nanotechnology Vol.23 No.33
<P>A novel displacement reaction has been observed to occur between conducting polymers (CP) and metal salts which can be used to fabricate nanostructured CP–metal composites in a one-pot manner. Vanadium pentoxide (V <SUB>2</SUB>O<SUB>5</SUB>) nanofiber is used during the synthesis as the reactive seeds to induce the nanofibril CP–metal network formation. The CP–metal nanocomposites exhibit excellent sensory properties for hydrogen peroxide (H<SUB>2</SUB>O<SUB>2</SUB>) detection, where both high sensitivity and a low detection limit can be obtained. The sensory performance of the CP–metal composite can be further enhanced by a facile microwave treatment. It is believed that the CP–metal nanofibril network can be converted to a carbon–metal network by a microwave-induced carbonization process and result in the sensory enhancement. </P>