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The Effect of pH on the Efficiency of an SBR Processing Piggery Wastewater
LiLong Yan,Yu Liu,Yuan Ren,Xiaohui Wang,Haijing Liang,Ying Zhang 한국생물공학회 2013 Biotechnology and Bioprocess Engineering Vol.18 No.6
To treat piggery wastewater efficiently, thehydrolysis of urea (mainly derived from swine urine) inpiggery wastewater with the change of sewage pH must beconsidered. Using activated sludge, piggery wastewaterwas treated in a sequencing batch reactor (SBR), and theeffects of influent pH on SBR processing efficiency, sludgesettle ability, and sludge activity were investigated. Theresults showed that a high influent pH value contributed tothe improvement of the removal rate of ammonia nitrogenand reduction of the chemical oxygen demand (COD). When the influent pH was between 9.0 and 9.5, the removalrate of ammonia nitrogen was higher than 90%, and thereduction of COD from its original value was 80%. Theinfluent pH had a greater influence on sludge concentrationand sludge activity. When the influent pH increased from7.0 to 9.5, the sludge concentration increased from 2,350 to3,947 mg/L in the reactor, and the activities of ammoniumoxidizing bacteria (AOB) and nitrite oxidizing bacteria(NOB) first increased and then decreased. When theinfluent pH was 9.0 and 8.0, the maximum values (0.48 gO2/(g MLSS/day) and 0.080 g O2/(g MLSS/day)) werereached, and the sludge settling ratio was nearly steadybetween 20 and 35% in each reactor.
Biosorption mechanism of Zn from aqueous solution by spent substrates of pleurotus ostreatus
XiaoJing Hu,JuanJuan Qu,LiLong Yan,Haidong Gu,TingTing Zang,Yu Jin 한국화학공학회 2014 Korean Journal of Chemical Engineering Vol.31 No.11
To solve the problem of heavy metal pollution and agricultural wastes reclamation, spent substrate of pleurotusostreatus (SSPO) was used as adsorbent to remove Zn2+from aqueous solution. The biosorption of zinc ions on SSPOwas studied as a function of the solution pH, temperature and initial Zn2+concentration. The equilibrium sorption datawere well represented by linear Langmuir isotherm models with R2value of 0.9955 and non-linear Freundlich withR2value of 0.9973. The BET surface area of SSPO can reach 51.16 m2g−1. SEM-EDX and XRD revealed that (NH4)2Zn·H2O and Zn2PO4(OH) were the main compounds in metal-loaded SSPO. FTIR analysis indicated the governing func-tional groups such as O-H, N-H and P=O played an important role in biosorption. The desorption studies showed thereversibility of SSPO. The results indicate that SSPO is a potential adsorbent in wastewater treatment due to its greatsorption capacity and low cost.