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Shuai Sun,Liang Li,Chao Wang,Hongyu Zhang 대한조선학회 2018 International Journal of Naval Architecture and Oc Vol.10 No.1
In order to analyze the characteristics of propeller exciting force, the hybrid grid is adopted and the numerical prediction of KCS ship model is performed for hullepropellererudder system by Reynolds-Averaged Navier Stokes (RANS) method and volume of fluid (VOF) model. Firstly, the numerical simulation of hydrodynamics for bare hull at oblique state is carried out. The results show that with the increasing of the drift angle, the coefficients of resistance, side force and yaw moment are constantly increasing, and the bigger the drift angle, the worse the overall uniformity of propeller disk. Then, propeller bearing force for hullepropellererudder system in oblique flow is calculated. It is found that the propeller thrust and torque fluctuation coefficient peak in drift angle are greater than that in straight line navigation, and the negative drift angle is greater than the positive. The fluctuation peak variation law of coefficient of side force and bending moment are different due to various causes.
Yan Zhao,Hongyu Liang,Dandan Wu,Junjia Bian,Yanping Hao,Guibao Zhang,Sanrong Liu,Huiliang Zhang,Lisong Dong 한국고분자학회 2015 폴리머 Vol.39 No.2
Poly(1,2-propylene glycol adipate) (PPA) was used as an environmentally friendly plasticizer in flexible poly(vinyl chloride) (PVC). Thermal, mechanical, and rheological properties of the PVC/PPA blends were characterized by differential scanning calorimetry, dynamic mechanical analysis, tensile test, scanning electron microscopy and small amplitude oscillatory shear rheometry. The results showed that PPA lowered the glass transition temperature of PVC. The introduction of PPA could decrease tensile strength and Young’s modulus of the PVC/PPA blends; however, elongationat-break was dramatically increased due to the plastic deformation. The plasticization effect of PPA was also manifested by the decrease of dynamic storage modulus and viscosity in the melt state of the blends. The results indicated that PPA had a good plasticizing effect on PVC.
Core@shell MOFs derived Co2P/CoP@NPGC as a highly-active bifunctional electrocatalyst for ORR/OER
Weijia Gong,Hongyu Zhang,Liuyang Zhou,Ya Yang,Jiashuo Wang,Heng Liang 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.106 No.-
In this study, Co2P/CoP hybrid nanoparticles (NPs) imbedded on the surface of core–shell metal–organicframeworks (MOFs) derived three-dimensional N, P co-doped graphitized carbon (Co2P/CoP@NPGC) areprepared via direct pyrolysis of P-containing MOF precursors. P dopant dosage is tailored to adjust activesites and crystalline phases of Co2P/CoP@NPGC. The active Co2P and CoP NPs and the synergistic effectfrom the Co-Nx/C and Co-P/C active sites and porous NPGC make the dominant contributions to theORR/OER. For ORR, the half-wave potential of Co2P/CoP@NPGC-1 is 0.93 V, which is superior to that ofPt/C (E1/2 = 0.875 V). As for OER, Co2P/CoP@NPGC-1 displays a lower overpotential (ƞ = 340 mV) comparedto RuO2 (ƞ = 380 mV, at 10 mA cm2). The Co2P@CoOOH heterojunction guarantees intrinsic conductivity. Furthermore, doping with N and P can modify the surface electronic structure of catalyst to lower theenergy of oxygen adsorption and dissociation, which are beneficial to enhance the ORR and OER activity. Additionally, its bifunctional activity parameter (DE) for ORR and OER is only 0.64 V, which is lower thanthat of Pt/C and RuO2 (0.76 V). Therefore, this work proposes a new sight into constructing a competitivecore–shell MOFs derived electrocatalyst for ORR/OER.
Hongwei Ren,Hongyu Dong,Tengda Zhao,Zhongqing Yan,Benzhen Jia,Liang Han,Jinfeng Zhang 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.127 No.-
Activated carbon (AC) is one of the typical adsorbents for industrial treatment of VOCs, but AC itself has ahigh calorific value. When the heat generated by low-temperature oxidation cannot be released, it is easyto store heat and oxidize spontaneously, resulting in immeasurable harm. Therefore, it is important tostudy and improve the thermal stability of AC. In this study, Mo-doped carbon quantum dots (CQDs)was synthesized to enhance the safety of AC usage. The structure of AC before and after modificationwas characterized by transmission electron microscope (TEM), Fourier transform infrared spectroscopy(FT-IR) and X-ray diffractometer (XRD). On the modified Mo-doped CQDs/AC, there are more crystallinestructures formed by Mo oxides on the surface, which makes the intermolecular force on the surface ofAC increase. At the same time, Mo oxide has strong oxidation resistance, which can inhibit the thermaldecomposition process of AC, and has stronger stability. The spontaneous combustion tendency and thermalhazard of AC before and after modification were greatly improved. The heat released in the tolueneadsorption by the modified AC at different temperatures was significantly lower than the heat released bythe unmodified AC. According to the Langmuir adsorption isotherm, the adsorption performance of ModopedCQDs (2.5 wt%) was 1.6 times higher than that of AC when the system was 25 C. The resultsshowed that Na2MoO4 CQDs modified AC could effectively improve the thermal stability and greatlyreduce the spontaneous combustion tendency. A relative fire safety performance evaluation model wasalso established to comprehensively evaluate the fire risk of VOCs treatment by AC.
Sun, Shuai,Li, Liang,Wang, Chao,Zhang, Hongyu The Society of Naval Architects of Korea 2018 International Journal of Naval Architecture and Oc Vol.10 No.1
In order to analyze the characteristics of propeller exciting force, the hybrid grid is adopted and the numerical prediction of KCS ship model is performed for hull-propeller-rudder system by Reynolds-Averaged Navier Stokes (RANS) method and volume of fluid (VOF) model. Firstly, the numerical simulation of hydrodynamics for bare hull at oblique state is carried out. The results show that with the increasing of the drift angle, the coefficients of resistance, side force and yaw moment are constantly increasing, and the bigger the drift angle, the worse the overall uniformity of propeller disk. Then, propeller bearing force for hull-propeller-rudder system in oblique flow is calculated. It is found that the propeller thrust and torque fluctuation coefficient peak in drift angle are greater than that in straight line navigation, and the negative drift angle is greater than the positive. The fluctuation peak variation law of coefficient of side force and bending moment are different due to various causes.