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Mengmeng Chen,Faizal Soyekwo,Qiugen Zhang,Chuan Hu,Aimei Zhu,Qinglin Liu 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.63 No.-
Polymers of intrinsic microporosity (PIMs) have attracted increasing interest in gas separation membranes due to their high permeability. However, the moderate selectivity limits their wide applications in CO2 separation. Herein we report a facile strategy to improve simultaneously the permeability and CO2 selectivity of PIMs membrane using the prepared PIM-1/graphene oxide (GO) nanosheets mixed matrix membrane. The GO nanosheets improves the hydrophilicity and surface roughness of PIM-1 membrane whereas the uniform assembly of GO nanosheets in the PIM-1 matrix creates the hydrophilic/hydrophobic microphase segregation in the membrane. The as-prepared mixed matrix membrane is also very porous and has a pore size of about 0.78 nm. The combination of these properties significantly contributes to the enhancement of the gas separation performance of PIM-1 membrane, with the resultant membrane exhibiting an exceptionally high CO2 permeability of up to 6169 barrer as well as a high CO2/N2 selectivity of 123.5, which is more than 7 times that of the pure PIM-1 membrane. The developed PIM-1/GO mixed matrix membrane should have a wide application in the CO2 separation.
Ruixue Lv,Faizal Soyekwo,Qiugen Zhang,Runsheng Gao,Jianyang Wu,Yan Qu,Aimei Zhu,Qinglin Liu 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.49 No.-
Polymer mesoporous membranes are widely employed in many membrane processes includingultrafiltration and dialysis, and become more crucial with increasing demand in chemical and lifefields. Here we report a highly-efficient polymer membrane with sub-5 nm pores and highflux frompolyacrylonitrile (PAN) nanoparticles produced from dilute PAN solution via fast freeze-extractionprocess. The25 nm-size PAN nanoparticles forming brad-like chains are dispersed in ethanol solutionand used to prepare the membrane byfiltration-assisted assembly method across a macroporoussupport. Effects of solvents and usage of PAN on membrane formation is studied in detail. The resultantmembranes comprise of the nanoparticles stacked on the support to form a mesoporous separation layerwith a controllable thickness and a cut-off of below 5 nm. They exhibit excellent separation performancesin ultrafiltration of protein and nanoparticle solutions. Typically, the membrane with 94.6% rejection of5 nm gold nanoparticles has a pure waterflux of 823 L m 1 h 1 bar 1 and perfect rejection for ferritinmolecules and 10 nm gold nanoparticles. The newly developed membranes should have wide applicationin chemical, environment and lifefields.