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RISS 인기검색어
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- 저자 : Donghua Yang (검색결과 3 건)
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Highly Selective Amination of o- and p-Alkyl Phenols over Pd/Al<sub>2</sub>O<sub>3</sub>-BaO
Ma, Jianchao,Wang, Huabang,Sun, Meng,Yang, Fan,Wu, Zhiwei,Wang, Donghua,Chen, Ligong Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.2
A series of Pd-based catalysts were prepared and examined for the amination of 2,6-dimethylphenol in a fixedbed reactor. The best results were obtained for Pd/$Al_2O_3$-BaO with a conversion of 99.89% and a selectivity of 91.16%. These catalysts were characterized using BET, XRD, XPS, TEM and $NH_3$-TPD. Doped BaO not only improved the dispersion of the Pd particles but also decreased the acidity of the catalyst, which remarkably enhanced the selectivity and stability of the catalyst. The generality of Pd/$Al_2O_3$-BaO for this kind of reaction was demonstrated by catalytic aminations of o- and p-alkyl phenols.
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Study on axial compressive behavior of quadruple C-channel built-up cold-formed steel columns
Shaofeng Nie,Tianhua Zhou,Fangfang Liao,Donghua Yang 국제구조공학회 2019 Structural Engineering and Mechanics, An Int'l Jou Vol.70 No.4
In this study, the axial compressive behavior of novel quadruple C-channel built-up cold-formed steel columns with different slenderness ratio was investigated, using the experimental and numerical analysis. The axial compressive capacity and failure modes of the columns were obtained and analyzed. The finite element models considering the geometry, material and contact nonlinearity were developed to simulate and analyze the structural behavior of the columns further. There was a great correlation between the numerical analyses and test results, which indicated that the finite element model was reasonable and accurate. Then influence of, slenderness ratio, flange width-to-thickness ratio and screw spacing on the mechanical behavior of the columns were studied, respectively. The tests and numerical results show that due to small slenderness ratio, the failure modes of the specimens are generally local buckling and distortional buckling. The axial compressive strength and stiffness of the quadruple C-channel built-up cold-formed steel columns decrease with the increase of maximum slenderness ratio. When the screw spacing is ranging from 150mm to 450mm, the axial compressive strength and stiffness of the quadruple C-channel built-up cold-formed steel columns change little. The axial compressive capacity of quadruple C-channel built-up cold-formed steel columns increases with the decrease of flange width-thickness ratio. A modified effective length factor is proposed to quantify the axial compressive capacity of the quadruple C-channel built-up cold-formed steel columns with U-shaped track in the ends.
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Highly Selective Amination of o- and p-Alkyl Phenols over Pd/Al2O3-BaO
Jianchao Ma,Huabang Wang,Meng Sun,Fan Yang,Zhiwei Wu,Donghua Wang,Ligong Chen 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.2
A series of Pd-based catalysts were prepared and examined for the amination of 2,6-dimethylphenol in a fixedbed reactor. The best results were obtained for Pd/Al2O3-BaO with a conversion of 99.89% and a selectivity of 91.16%. These catalysts were characterized using BET, XRD, XPS, TEM and NH3-TPD. Doped BaO not only improved the dispersion of the Pd particles but also decreased the acidity of the catalyst, which remarkably enhanced the selectivity and stability of the catalyst. The generality of Pd/Al2O3-BaO for this kind of reaction was demonstrated by catalytic aminations of o- and p-alkyl phenols.
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