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      • Design of Low Power and Secure Implementation of SBox and Inverse-SBox for AES

        Divya Sharma,Ankur Bhardwaj,Harshita Prasad,Jyoti Kandpal,Abhay Saxena,Kumar Shashi Kant,Gaurav Verma 보안공학연구지원센터 2016 International Journal of Security and Its Applicat Vol.10 No.7

        In the cutting edge world, data security has turned into an essential issue furthermore the innovation is going to increment quickly. In this paper, the symmetric key standard for encryption and decoding is propelled Encryption standard (AES). The key stride in the AES is the "S-Box". S Box is an imperative segment for symmetric key calculations. An S-box takes some number of information bits "p" and interprets them in yield bits 'q', where "p" is not as a matter of course equivalent to 'q'. In AES Encryption calculation Sub Bytes change uses S-Box and Inverse S-Box uses Inverse of S-Box. The Sub Bytes substitution is a nonlinear byte substitution that uses substitution table (i.e., S-Box) takes the multiplicative reverse (GF (28)) and infers a relative change to do the Sub Bytes change. Though, converse Sub Bytes Substitution additionally uses gaze upward table (i.e., Reverse S-Box) takes an opposite relative change and after that suggests multiplicative backwards of Galois Field (GF (28)). In this printed material, we investigated substitution table/reverse substitution table, multiplicative opposite and relative change and its converse (i.e. reverse relative change) science in Galois field. A standout amongst the most basic issues in AES is the force utilization. Here, we predominantly centered around the force utilization and in addition security of S-box which is the most power devouring square in the AES. We have executed and reproduced S-Box and Inverse S-Box Lookup table and acquired another improved scrambled Lookup table for more upgraded mystery by utilizing Xilinx Spartan-3 assessment board. The Simulation and execution instruments utilized are Xilinx ISE 14.1i and ModelSim 6.0.

      • KCI등재

        Synthesis, Thermal Studies and Spectral Characterization of Co(II), Ni(II), Cu(II), and Zn(II) Complexes with Some Polymeric Diacetyl Acyldihydrazone Ligands

        Vinod Prasad Singh,Divya Pratap Singh 한국고분자학회 2013 Macromolecular Research Vol.21 No.7

        Two polymeric ligands, diacetyl oxaloyldihydrazone (DODH), diacetyl malonoylhydrazone (DMDH)and their Co(II), Ni(II), Cu(II) and Zn(II) complexes were synthesized and characterized by elemental analyses, IR,mass, 1H & 13C NMR, ESR and electronic spectral studies. The ligands and their complexes are highly insoluble in water and common organic solvents and decompose at high temperature. The metal atoms are embedded between two polymeric chains of the organic ligands and the monomeric unit of the polymeric chain behaves as a neutral bidentate ligand and coordinate through two >C=N groups to different metals as indicated by 1H & 13C NMR and IR spectral studies. The molecular weights determined by 1H NMR and mass spectral studies suggest oligomeric nature of the ligands and their Zn(II) complexes. The magnetic susceptibility measurements and electronic spectral studies indicate a square planar geometry around the metal ion in Co(II) and Ni(II) complexes. Electronic and ESR spectral studies for Cu(II) complexes suggest a distorted octahedral stereochemistry around the metal atom and 2B1g as the ground state. Thermal studies (TGA and DTA) of some of the complexes in inert atmosphere show a multi-step exothermic decomposition of the bonded organic ligand at high temperature and metal (II) chloride as the end product.

      • An Ensemble Approach for Efficient Churn Prediction in Telecom Industry

        Pretam Jayaswal,Bakshi Rohit Prasad,Divya Tomar,Sonali Agarwal 보안공학연구지원센터 2016 International Journal of Database Theory and Appli Vol.9 No.8

        The rise of globalization and market liberalization are changing the face of market competitiveness significantly. The appearance of modern technology in business processes has intensified the competition and put forth new challenges for service providing companies. To cope up with changing scenarios, companies are shifting their attention on retaining the existing customers rather hiring new ones. This is more cost effective and requires lesser resource as well. The phenomenon of abandoning the company by a customer is known as churn and in this context, anticipating the customer's intention to churn is called churn prediction. Data Mining and machine learning techniques, as applied to customer behavior and usage information, can assist the churn management processes. This paper used customer usage and related information from a telecom service provider to analyze churn in telecom industry. The decision trees and its ensembles, Random Forest and Gradient Boosted trees are used as underlying statistical machine learning models for building the binary churn classifier. The implementation part has been done using apache spark which is state of the art unified data analysis framework for machine learning and data mining. In order to achieve better and efficient results, the grid based hyper-parameter optimization is applied.

      • KCI등재

        Selective vapour-phase dehydrocyclization of biomass-derived 1,4- butanediol to c-butyrolactone over Cu/ZnAl2O4-CeO2 catalyst

        Komal N. Patil,Divya Prasad,Vilas K. Manoorkar,Jayesh T. Bhanushali,Arvind H. Jadhav,Bhari Mallanna Nagaraja 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.106 No.-

        Production of c-butyrolactone (GBL) from vapour-phase dehydrocyclization of biomass derived 1,4-butanediol is considered as more sustainable and significantly commercial industrial process. In thisregards, Cu-based catalyst was designed with ZnAl2O4 spinel support and CeO2 as a promoter to obtainCu/ZnAl2O4-CeO2 catalyst with different Cu:Ce mass ratio. The catalysts were characterized by XRD,H2-TPR, FT-IR, CO2-TPD, FE-SEM and BET analysis and then tested for the production of cbutyrolactone(GBL) by dehydrocyclization of 1,4-butanediol (BDO). Further, various reaction parameterswere optimized and their effects on the catalytic activity were studied to obtain maximum yield towardsdesired product at ambient reaction conditions. The results revealed that metallic Cu species and CeO2 asa promoter were highly dispersed on ZnAl2O4 support with appreciable surface area. Additionally, CeO2as a promoter prevented agglomeration, increased the basic character of catalyst to selectively obtain GBLas a major product. 10 wt% Cu/ZnAl2O4-10 wt% CeO2 catalyst exhibited excellent yield (94%) towards GBLproduct with tetrahydrofuran (THF) as the only by-product and demonstrated consistent activity andselectivity during 26 h time on stream. Further, the optimized catalyst displayed appreciable recyclabilityperformance up to seven recycles without much loss in its catalytic performance making the catalyst feasibleat industrial scale.

      • Tailoring and exploring the basicity of magnesium oxide nanostructures in ionic liquids for Claisen-Schmidt condensation reaction

        Jadhav, Arvind H.,Prasad, Divya,Jadhav, Harsharaj S.,Nagaraja, Bhari Mallanna,Seo, Jeong Gil Elsevier 2018 ENERGY Vol.160 No.-

        <P><B>Abstract</B></P> <P>Solid basic catalysts are extremely useful for green catalytic processes because of their high activity, easy separation, and minimal corrosion. Herein, we report the development and effect of the basicity of five various MgO nanostructures developed by microwave (MW) irradiation in different ionic liquids (ILs) on the Claisen-Schmidt Condensation Reaction. The growth of the shape-controlled MgO nanostructures in the presence of the synergetic effect of the ILs with the MW irradiation developed various basic sites on the surface of the MgO nanocrystals. Due to the synergetic effect (formation of hydrogen bonding and π-π interactions between the ILs and the MgO precursor in the presence of MW irradiation) produced active basic sites in the final nanostructure. The TPD & XPS results show that the synergetic effect strongly altered the percentages of high, low, and moderate basic sites of the catalysts. To determine their catalytic activity based on the obtained different basicity in the MgO nanostructures, prepared all nano structures were tested in the reaction. The altered basicity of the MgO catalysts strongly affected on reaction results and demonstrated better activity than pure MgO. Particularly, hexagonal MgO nanostructures with exposed crystal facets (110) and (111) having high surface area and basicity showed an outstanding activity. In addition, effect or reaction parameters such as temperature, catalyst amount, solvent effect, and reaction time were determine and obtained optimized reaction condition for outstanding results. To determine the diversity of prepared MgO nanostructures, various substituted chalcones were prepared in optimized reaction condition in good to efficient yield. Recyclability of prepared catalyst was also determined up-to 6 cycles and physicochemical changes before and after recyclability test was determined. The proper correlation of obtained basicity & basic sites with the catalytic activity was established with this protocol.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Shape controlled MgO structures were used as catalysts having altered basicity. </LI> <LI> Altered basicity developed by ILs and MW irradiation while structure development. </LI> <LI> Exposed high surface with (110) (111) facets of MgO showed outstanding activity. </LI> <LI> Catalysts can be recycled without disturbing morphology and catalytic activity. </LI> <LI> New green approach for the alteration of basic sites in heterogeneous base catalysts. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

      • KCI등재

        Interleukin-1B (IL-1B-31 and IL-1B-511) and interleukin-1 receptor antagonist (IL-1Ra) gene polymorphisms in primary immune thrombocytopenia

        Deependra Kumar Yadav,Anil Kumar Tripathi,Divya Gupta,Saurabh Shukla,Aloukick Kumar Singh,Ashutosh Kumar,Jyotsna Agarwal,K. N. Prasad 대한혈액학회 2017 Blood Research Vol.51 No.4

        Background: Immune thrombocytopenia (ITP) is an immune-mediated disease caused by autoanti-bodies against platelets membrane glycoproteins GPIIb/IIIa and GPIb/IX. The etiology of ITP remains unclear. This study evaluated the association of polymorphisms in interleukin (IL)-1B-31, IL-1B-511, and IL-1Ra with ITP. Methods: Genotyping of IL-1B-31, IL-1B-511, and IL-1Ra was performed in 118 ITP patients and 100 controls by polymerase chain reaction restriction fragment length polymorphism and detection of variable number tandem repeats. Results: Genotype differences in IL-1B-31 and IL-1Ra were significantly associated with ITP. Patients showed a higher frequency of the IL-1B-31 variant allele (T) and a 1.52-fold greater risk of susceptibility to ITP (odds ratio [OR]=1.52, 95% confidence interval [CI]=1.04‒2.22, P=0.034). The frequencies of both homozygous and heterozygous variant geno-types of IL-1B-31 were higher (OR=2.33, 95% CI=1.069‒5.09, P=0.033 and OR=2.044, 95% CI=1.068‒39, P=0.034) among patients and were significantly associated with ITP susceptibility. Both homozygous and heterozygous variant genotypes of IL-1Ra were also more frequent (OR=4.48, 95% CI=1.17‒17.05, P=0.0230 and OR=1.80, 95% CI=1.03‒3.14, P=0.0494) among patients and were associated with ITP risk. IL-1B-31 and IL-1Ra also showed significant association with severe ITP. However, IL-1B-511 was not asso-ciated with ITP. Conclusion: IL-1B-31 and IL-1Ra polymorphisms may significantly impact ITP risk, and they could be associated with disease severity, which may contribute to the pathogenesis of ITP.

      • KCI등재

        Interleukin-1B (IL-1B-31 and IL-1B-511) and interleukin-1 receptor antagonist (IL-1Ra) gene polymorphisms in primary immune thrombocytopenia

        Deependra Kumar Yadav,Anil Kumar Tripathi,Divya Gupta,Saurabh Shukla,Aloukick Kumar Singh,Ashutosh Kumar,Jyotsna Agarwal,K. N. Prasad 대한혈액학회 2017 Blood Research Vol.52 No.4

        Background: Immune thrombocytopenia (ITP) is an immune-mediated disease caused by autoanti-bodies against platelets membrane glycoproteins GPIIb/IIIa and GPIb/IX. The etiology of ITP remains unclear. This study evaluated the association of polymorphisms in interleukin (IL)-1B-31, IL-1B-511, and IL-1Ra with ITP. Methods: Genotyping of IL-1B-31, IL-1B-511, and IL-1Ra was performed in 118 ITP patients and 100 controls by polymerase chain reaction restriction fragment length polymorphism and detection of variable number tandem repeats. Results: Genotype differences in IL-1B-31 and IL-1Ra were significantly associated with ITP. Patients showed a higher frequency of the IL-1B-31 variant allele (T) and a 1.52-fold greater risk of susceptibility to ITP (odds ratio [OR]=1.52, 95% confidence interval [CI]=1.04‒2.22, P=0.034). The frequencies of both homozygous and heterozygous variant geno-types of IL-1B-31 were higher (OR=2.33, 95% CI=1.069‒5.09, P=0.033 and OR=2.044, 95% CI=1.068‒39, P=0.034) among patients and were significantly associated with ITP susceptibility. Both homozygous and heterozygous variant genotypes of IL-1Ra were also more frequent (OR=4.48, 95% CI=1.17‒17.05, P=0.0230 and OR=1.80, 95% CI=1.03‒3.14, P=0.0494) among patients and were associated with ITP risk. IL-1B-31 and IL-1Ra also showed significant association with severe ITP. However, IL-1B-511 was not asso-ciated with ITP. Conclusion: IL-1B-31 and IL-1Ra polymorphisms may significantly impact ITP risk, and they could be associated with disease severity, which may contribute to the pathogenesis of ITP.

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