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Chaocheng Zhao,Shuaijun Wang,Qingyun Yan,Pei Dong,Yongqiang Wang,Fang Liu,Lin Li 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.7
Rational design and construction of Z-scheme photocatalysts have received much attention in the fields of organic pollutants degradation and H2 evolution because of their potentials to solve the current environmental and energy crises. Herein, a novel nitrogen defects-rich 0D/2D α-Fe2O3/g-C3N4 Z-scheme photocatalyst was fabricated via a one-pot co-pyrolysis method. Quantum-sized α-Fe2O3 dots with a diameter of approximately 5 nm were uniformly distributed on the surface of 2D g-C3N4. Besides, the prepared 0D/2D α-Fe2O3/g-C3N4 composites exhibited excellent RhB degradation ability and simultaneous H2 evolution efficiency. In comparison with 2D g-C3N4, the RhB degradation rate and H2 evolution catalyzed by 0D/2D α-Fe2O3/g-C3N4 were enhanced 3.9 and 1.8 times, respectively. The improved photoredox activity was predominantly attributed to the formation of the nitrogen defects and a Z-scheme heterojunction. This study provides novel insights into the design and fabrication of nitrogen defects-rich g-C3N4-based Z-scheme photocatalysts for the simultaneous environmental purification and H2 evolution.
Hongbin Yang,Shuo Shao,Tongyu Zhu,Chaocheng Zhao,Shuren Liu,Bobo Zhou,Xiaoyu Hou,Yang Zhang,Wanli Kang 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.79 No.-
Low elastic polymer microsphere (L-EPM) has been proposed as a functional polymer microsphere theseyears. L-EMP has the excellent deformation ability in the porous medium due to the low storage modulus. Herein, one kind of L-EPM with storage modulus (G0) of 23.6 Pa was prepared by inverse suspensionpolymerization. The shear resistance of L-EPM was researched by using coreflooding experiment andhigh shear rate emulsifier. The conformance control behavior of L-EPM was investigated by using doubleparallel sandpackflooding experiment. The results showed that L-EPM was a kind of swollen particle gelwith three-dimensional net structure and contained amide, carboxyl, and sulfonate groups. Themechanism of water swelling property was mainly due to the formation of hydrogen bonds, hydrolysis ofhydrophilic groups and the diffusion caused by osmotic pressure difference. Compared with high elasticpolymer microspheres (H-EPM) and low elastic preformed particle gel (L-PPG), L-EPM had better shearresistance in the porous medium and the well casing perforation. In addition, the critical shear points ofL-EPM was proposed in this work. Due to the better shear resistance and deformation ability, theconformance control behavior of L-EPM showed that L-EPM was a promising conformance control agentin the heterogeneous reservoirs.