http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Debajeet K. Bora,Artur Braun,Selma Erat,Olga Safonova,Thomas Graule,Edwin C. Constable 한국물리학회 2012 Current Applied Physics Vol.12 No.3
Iron oxide nano particles with nominal Fe2O3 stoichiometry were synthesized by a wet, soft chemical method with heat treatment temperatures from 250 ℃ to 900 ℃ in air. The variation in the structural properties of the nano particles with the heat treatment temperature was studied by X-ray diffraction and Fe K-shell X eray absorption spectroscopy. X-ray diffractograms show that at lower annealing temperatures the nano particle comprise both maghemite and hematite phases. With increasing temperature, the remainder of the maghemite phase transforms completely to hematite. Profile analysis of the leading Bragg reflections reveals that the average crystallite size increases from 50 nm to 150 nm with increasing temperature. The mean primary particle size decreases from 105 nm to 90 nm with increasing heat treatment temperature. The X-ray diffraction results are paralleled by systematic changes in the pre-edge structure of the Fe K-edge X-ray absorption spectra, in particular by a gradual decrease of the t2g/eg peak height ratio of the two leading pre-edge resonances, confirming oxidation of the Fe from Fe2+ towards Fe3+. Transmission electron microscopy (TEM) on the samples treated at temperatures as high as 900 ℃ showed particles with prismatic morphology along with the formation of stacking fault like defects. High resolution TEM with selected area electron diffraction (SAED) of samples heat treated above 350 C showed that the nano particles have well developed lattice fringes corresponding to that of (110) plane of hematite.
Faccio Greta,Gajda-Schrantz Krisztina,Ihssen Julian,Boudoire Florent,Hu Yelin,문봉진,Bora Debajeet K,Thöny-Meyer Linda,Braun Artur 나노기술연구협의회 2015 Nano Convergence Vol.2 No.9
Functionalization of the hematite photoanode with the photosynthetic light antenna protein C-phycocyanin (PC) can yield substantial enhancement of the photocurrent density. Photoelectrochemical cells with bio-hybrid electrodes from photosynthetic proteins and inorganic semiconductors have thus potential for the use in artificial photosynthesis. We investigate here processing routes for the functionalization of hematite photoanodes with PC, including in situ co-polymerization of PC with enzymatically-produced melanin, and using a recombinant PC genetically engineered to carry a hexa-histidine tag (αHisPC). First, the effect of the immobilisation of PC on the electrode morphology and photocurrent production is evaluated. Then, the electronic charge transfer in dark and light conditions is assessed with electrochemical impedance spectroscopy and valence band (VB) X-ray photoemission spectroscopy. The relative shift of the VB spectrum towards the Fermi energy E F upon illumination is smaller for the more complex processed coating and virtually disappears for αHisPC immobilised with a melanin film. Optimal conditions for protein immobilisation are determined and the dark currents benefit most from the most advanced protein coating processes.