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Iraj Jodan,Kitirote Wantala,Nader Amini,Behzad Shahmoradi,Mona Ghaslani,이승목,Jixiang Yang,Shivaraju Harikaranahalli Puttaiah 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.9
The harmful and destructive effects of excessive consumption of thiourea in various industries and agriculture have caused health and environmental concerns. Hence, attention has been paid to the need for analysis and detection thiourea at very low concentrations. The aim of this study was to determine the efficiency of electrochemical sensor based on glass carbon electrode modified with Ag nanoparticles and alizarin yellow to detect thiourea as a pollutant. Glass carbon electrode was first modified by alizarin yellow polymer and Ag nanoparticles through electropolymerization and chronoamperometry methods, respectively. The characteristics of the modified electrode were determined through FESEM and EDAX analysis and thiourea concentration was measured through cyclic voltammetry (CV) and differential pulse voltammetry (DPV) methods. The results showed that the linear range, limit of detection, and sensitivity were 10 to 940 M, 3.3 M and 0.181 A/M, respectively. The stability and reproducibility of the sensor response as well as the interference effect of some anion species were investigated on the performance of the sensor in determining thiourea. The results indicate the optimum stability and reproducibility and no interference effect of the studied species on efficiency of the sensor in determining thiourea.
Roya Ebrahimi,Afshin Maleki,Yahya Zandsalimi,Reza Ghanbari,Behzad Shahmoradi,Reza Rezaee,Mahdi Safari,주상우,Hiua Daraei,Shivaraju Harikaranahalli Puttaiah,Omid Giahi 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.73 No.-
The present study aimed at evaluating the application of tungsten oxide-doped zinc oxide nanoparticlesfor the photocatalytic degradation of Direct Blue 15 dye in a sequencing batch reactor. ZnO nanoparticleswere doped with WO3 through hydrothermal synthesis method. To characterize the synthesizednanoparticles scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy,atomic force microscopy, zeta potential analysis, and ultraviolet–visible spectroscopy were used. Theradiation source in this study wasfive 6 W UV lamps. Operational parameters affecting the process,namely pH, light intensity, dopant percentage, dye concentration, and contact time, were evaluated. Theresults of the present study revealed that the efficiency of the photocatalytic process for the degradationof organic dyes was higher at acidic pH values than neutral or basic values. In addition, upon increasingthe light intensity from 172 to 505 W/m2, the efficacy of dye degradation was enhanced from 27.8 to73.5%. Increasing the concentration of the dopant percentage from 1 to 5% w/v increased the degradationefficacy from 30.69 to 73.1%. Increasing the initial dye concentration from 20 to 100 mg/L decreased thedegradation efficacy from 86.9 to 37.5%. Photocatalytic process using WO3-doped ZnO nanoparticlesfixedon a glass surface thus was proven to show a good efficiency for the degradation of organic dye in aquaticsolutions.