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      • Innovative method to prepare a stable emulsion liquid membrane for high CO<sub>2</sub> absorption and its performance evaluation for a natural gas feed in a rotating disk contactor

        Bhatti, Inamullah,Qureshi, Khadija,Kamarudin, Khairul Sozana Nor,Bazmi, Aqeel Ahmed,Bhutto, Abdul Waheed,Ahmad, Faizan,Lee, Moonyong Elsevier 2016 Journal of natural gas science and engineering Vol.34 No.-

        <P><B>Abstract</B></P> <P>This paper presents an innovative method to prepare a stable emulsion liquid membrane (ELM) for high CO<SUB>2</SUB> absorption in a natural gas feed. This new method achieved high throughput at low power consumption. The ELM prepared using this new method was characterized by determining the effects of the concentration of the ELM constituents, emulsification time, and speed on the emulsion droplet size (EDS) and stability. This was followed by a parametric study of the process parameters for CO<SUB>2</SUB> separation from natural gas in a rotating disk contactor (RDC)-based setup to evaluate the performance of a stable ELM. The results suggest that the retention time of the stable ELM in a RDC increases with increasing amount of absorbed CO<SUB>2</SUB>. The results support the fundamental development of the ELM process to achieve a high overall separation efficiency of CO<SUB>2</SUB> removal from natural gas with a relatively small contact time. This is the first parametric study of CO<SUB>2</SUB> absorption from a gas stream in ELM using a RDC as the contracting equipment. The results of the parametric study suggested that the factors of time, TEA concentration and RDC speed have significant effect on the CO<SUB>2</SUB> absorption from natural gas feed. It was identified that 4% TEA in ELM, 30 min operational time and 700 rpm speed of modified RDC system is suitable for maximum CO<SUB>2</SUB> absorption from gas mixture of CO<SUB>2</SUB>/CH<SUB>4</SUB>. Furthermore, the study suggested that the ELM containing 4% TEA can absorb 5.6 kmol/m<SUP>3</SUP> CO<SUB>2</SUB>.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Preparation and characterization of stable emulsion liquid membrane (ELM). </LI> <LI> Parametric study of CO<SUB>2</SUB> absorption from natural gas in rotating disk contactor (RDC). </LI> <LI> Retention time of the stable ELM increases with increasing amount of absorbed CO<SUB>2</SUB>. </LI> <LI> Fundamental development of ELM process for high overall separation efficiency. </LI> </UL> </P>

      • Membrane separation processes for dehydration of bioethanol from fermentation broths: Recent developments, challenges, and prospects

        Khalid, Azqa,Aslam, Muhammad,Qyyum, Muhammad Abdul,Faisal, Abrar,Khan, Asim Laeeq,Ahmed, Faisal,Lee, Moonyong,Kim, Jeonghwan,Jang, Nulee,Chang, In Seop,Bazmi, Aqeel Ahmed,Yasin, Muhammad Elsevier 2019 RENEWABLE & SUSTAINABLE ENERGY REVIEWS Vol.105 No.-

        <P><B>Abstract</B></P> <P>Bioethanol has garnered a great interest as a potential energy source, mainly due to its sustainable and green nature. Generally, bioethanol is produced through the microbial conversion of biomass and biomass derived syngas. However, the dehydration and purification steps for achieving fuel-grade ethanol from the microbial production process consume tremendous amounts of energy. This high energy consumption limits the feasibility of microbial ethanol production on the commercial scale. In this context, selection of an optimal technology for product separation is essential for successful commercialization of microbially produced bioethanol. This article presents the recent developments in dehydration and purification technologies for bioethanol production using distillation and membrane based separation. Distillation and pervaporation are analyzed on the basis of the overall energy requirement, consumption, and economics. Pervaporation-assisted distillation approaches are also examined from the perspective of process systems engineering, including factors affecting the system performance. Furthermore, the role of simulation in technological development along with available mathematical models is discussed, and commercial status of pervaporation based separation is presented. Finally, the current status of the existing technology, challenges, and future research directions are identified from the perspective of achieving process sustainability on the industrial scale. Economic comparison between distillation and different hybrid schemes revealed that integrating distillation with membrane based separation techniques reduce the bioethanol production cost. Moreover, hybrid schemes that combine distillation with pervaporation, and steam stripping with vapor permeation are proved to be the best combinations for the cheapest bioethanol production.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Recent developments in dehydration of bioethanol are presented. </LI> <LI> Conventional and membrane-based technologies are compared. </LI> <LI> Integrating pervaporation with distillation reduce the bioethanol production cost. </LI> <LI> The most economical hybrid schemes for bioethanol separation is identified. </LI> <LI> Operational optimization and thermodynamic evaluation of hybrid processes are required. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

      • KCI등재

        An overview of the role of ionic liquids in biodiesel reactions

        Nawshad Muhammad,Yasir A. Elsheikh,Muhammad Ibrahim Abdul Mutalib,Zakaria Man,Ihsnullah khan,Aqeel Ahmed Bazmi,Rahmat Ali Khan,Hidayatullah Khan,Sikander Rafiq 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.21 No.1

        The concerns on the depleting petroleum resources and increasing environmental problems have driventhe scientific community worldwide to develop large-scale non-petroleum-based alternative fuels, suchas bioethanol and biodiesel. Biodiesel produced through the transesterification of vegetable oils oranimal fats are highly attractive. On the other hand, ionic liquids which possess properties that aremoreenvironmental friendly have found significant applications as solvents and catalysts for reaction andseparation. It is also beginning to find its way in many of the chemical process applications and hasattracted significant attention including biodiesel production. This paper provides a brief overview onthe feasibility of applying ionic liquids in biodiesel production for the purpose of powering diesel enginesfor transportation and utility generation. The potential of applying ionic liquids as catalyst and solventfor enzymatic production of biodiesel from feedstock is particularly highlighted.

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