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Akbar Zare,Mehdi Shiva,Ahad Zare,Ali Akbar Mirzaei 한국공업화학회 2013 Journal of Industrial and Engineering Chemistry Vol.19 No.6
The Co–Ni/Al2O3 catalysts prepared using impregnation procedure, were used for the Fischer–Tropsch synthesis. The effect of calcination conditions of the catalyst as well as reactor situation was studied. It was found that the catalyst calcined at 550 8C for 6 h in air atmosphere has shown the best catalytic performance for CO hydrogenation. The best operational conditions were obtained as following:T = 350 8C, P = 1 atm and H2/CO = 2/1.
Ali Akbar Abbasian Arani,Ali Akbar Azemati,Mohammad Rezaee,Behzad Shirkavand Hadavand 대한기계학회 2017 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.31 No.5
Natural convection in enclosures containing nanofluids is important in physical and environmental applications. Different models for conduction have been developed because of the importance of this phenomenon in natural convection in enclosures. In this study, effects of conduction models of Chon, Corcione, Khanafer, and Koo and Kleinstreuer on the natural convection inside a trapezoidal enclosure with hot and cold walls are evaluated numerically. The enclosure contains Al 2 O 3 -water nanofluid with variable properties. Effects of the conduction models on fluid flow, natural convection, variations in volume fraction, and diameter of nanoparticles in the models, as well as the variations in the Rayleigh number, are examined. Results show that at Rayleigh numbers of 10 5 and 10 6 , the maximum and minimum values of the average Nusselt number are obtained using the models of Khanafer and Chon, respectively. In all models, the average Nusselt number presents upward and downward trends when the volume fraction of nanoparticles increases but decreases when the diameter of the nanoparticles increases. At Ra = 10 5 in all models, as the volume fraction of nanoparticles increases, the nanofluid provides a higher average Nusselt number compared with the base fluid. By contrast, at Ra = 10 6 , at volume fractions larger than 0.01 and using the model of Chon, the average Nusselt number of the nanofluid is lower compared with that of the base fluid.
A brief review on graphene applications in rechargeable lithium ion battery electrode materials
Sameen Akbar,Muhammad Rehan,Liu Haiyang,Iqra Rafique,Hurria Akbar 한국탄소학회 2018 Carbon Letters Vol.28 No.-
Graphene is a single atomic layer of carbon atoms, and has exceptional electrical, mechanical, and optical characteristics. It has been broadly utilized in the fields of material science, physics, chemistry, device fabrication, information, and biology. In this review paper, we briefly investigate the ideas, structure, characteristics, and fabrication techniques for graphene applications in lithium ion batteries (LIBs). In LIBs, a constant three-dimensional (3D) conductive system can adequately enhance the transportation of electrons and ions of the electrode material. The use of 3D graphene and graphene-expansion electrode materials can significantly upgrade LIBs characteristics to give higher electric conductivity, greater capacity, and good stability. This review demonstrates several recent advances in graphenecontaining LIB electrode materials, and addresses probable trends into the future.
A Product Inhibition Study on Adenosine Deaminase by Spectroscopy and Calorimetry
(Ali Akbar Saboury),(Ghasem Ataie Jafari),(Ali Akbar Moosavi Movahedi),(Mohammad Reza Housaindokht),(Gholam Hosain Hakimelahi),(Adeleh Divsalar) 생화학분자생물학회 2002 BMB Reports Vol.35 No.3
Kinetic and thermodynamic studies have been made on the effect of the inosine product on the activity of adenosine deaminase in a 50 mM sodium phosphate buffer, pH 7.5, at 27oC using UV spectrophotometry and isothermal titration calorimetry (ITC). A competitive inhibition was observed for inosine as a product of the enzymatic reaction. A graphical-fitting method was used for determination of the binding constant and enthalpy of inhibitor binding by using isothermal titration microcalorimetry data. The dissociation-binding constant is equal to 140 μM by the microcalorimetry method, which agrees well with the value of 143 μM for the inhibition constant that was obtained from the spectroscopy method.
A Product Inhibition Study on Adenosine Deaminase by Spectroscopy and Calorimetry
Saboury, Ali Akbar,Divsalar, Adeleh,Jafari, Ghasem Ataie,Moosavi-Movahedi, Ali Akbar,Housaindokht, Mohammad Reza,Hakimelahi, Hosain 생화학분자생물학회 2002 Journal of biochemistry and molecular biology Vol.35 No.3
Kinetic and thermodynamic studies have been made on the effect of the inosine product on the activity of adenosine deaminase in a 50 mM sodium phosphate buffer, pH 7.5, at $27^{\circ}C$ using UV spectrophotometry and isothermal titration calorimetry (ITC). A competitive inhibition was observed for inosine as a product of the enzymatic reaction. A graphical-fitting method was used for determination of the binding constant and enthalpy of inhibitor binding by using isothermal titration microcalorimetry data. The dissociation-binding constant is equal to $140\;{\mu}M$ by the microcalorimetry method, which agrees well with the value of $143\;{\mu}M$ for the inhibition constant that was obtained from the spectroscopy method.
Distance transform algorithm for measuring nanofiber diameter
Akbar Khodaparast Haghi,Mohammad Ziabari,Vahid Mottaghitalab 한국화학공학회 2008 Korean Journal of Chemical Engineering Vol.25 No.4
This paper describes a new distance transform method used for measuring fiber diameter in electrospun nanofiber webs. In this algorithm, the effect of intersection is eliminated, which brings more accuracy to the measurement. The method is tested by a series of simulated images with known characteristics as well as some real webs obtained from electrospinning of PVA. Our method is compared with the distance transform method. The results obtained by our method were significantly better than the distance transform, indicating that the new method could successfully be used to measure electrospun fiber diameter
Akbar Hassan,Javed Muhammad Subhan,Iqbal Syeda Tehreem,Khan Muhammad Iftikhar,Anwar Tauseef,Anjum Faiza,Ahmad Ashfaq,Muneeb Muhammad,Ali Asghar,Won Chun Oh 한국세라믹학회 2024 한국세라믹학회지 Vol.61 No.3
To mitigate the increased CO 2 emission, CO 2 reduction to multi-carbon fuels or other useable substances is an appealing yet essential approach. Since, reduction of CO 2 is a thermodynamically uphill process, an economical CO 2 fi xation is only achievable if energy source used is of renewable energy such as solar energy. Photocatalytic CO 2 reduction is a complex pro- cess due to its dependency on catalyst design, selectivity, effi ciency, and photostability. The competence of a photocatalytic CO2 reduction reaction is eff ected by factors, such as the type of photocatalyst used their band-gap energy, surface area, and structure of the crystal. This review discusses the kinetics and thermodynamics of photocatalytic CO 2 reduction and consid- ers the eff ects of parameters like defects and impurity doping on photocatalysis. The study also focusses on the selectivity of products, i.e., methane, methanol, formaldehyde, etc. This comprehensive review provides insights into the development and improvement of photocatalytic effi ciency for CO 2 photoreduction, contributing to the reduction of carbon emissions and a more sustainable future.
Akbar, Kamran,Hussain, Sajjad,Truong, Linh,Roy, Sanjib Baran,Jeon, Jae Ho,Jerng, Sahng-Kyoon,Kim, Minsoo,Yi, Yeonjin,Jung, Jongwan,Chun, Seung-Hyun American Chemical Society 2017 ACS APPLIED MATERIALS & INTERFACES Vol.9 No.50
<P>Despite tremendous progress in the development of novel electrocatalysts for hydrogen evolution reaction (HER), the accumulation, of hydrogen gas bubbles produced on the catalyst surface has been rather poorly addressed. The bubbles block the surface of the electrode, thus resulting in poor performance even when excellent electrocatalysts are used. In this study, we show that vertically grown graphene nanohills (VGNHs) possess an excellent capability to quickly disengage the produced hydrogen gas bubbles from the electrode surface, and thus exhibit superaerophobic properties. To compensate for the poor electrolytic properties of graphene toward HER, the graphene surface was modified with WS2 nanoparticles to accelerate the water-splitting process by using this hybrid catalyst (VGNHs-WS2). For comparison purposes, WS2 nanoparticles were also deposited on the flat graphene (FG) surface. Because of its superior superaerophobic properties, VGNHs-WS2 outperformed FG-WS2 in terms of both catalytic activity toward the HER and superaerophobicity. Furthermore, VGNHs-WS2 exhibited a low onset potential (36 mV compared to 288 mV for FG-WS2) and long-term stability in the HER over an extended period of 20 h. This study provides an efficient way to utilize highly conductive and superaerophobic VGNHs as support materials for intrinsic semiconductors, such as WS2, to simultaneously achieve superaerophobicity and high catalytic activity.</P>
MINIMUM PENDANT DOMINATING ESTRADA INDEX OF A GRAPH
AKbar Jahanbani,Ismail Naci CANGUL 장전수학회 2020 Advanced Studies in Contemporary Mathematics Vol.30 No.4
The main purpose of this paper is to introduce the con- cept of minimum pendant dominating Estrada index of a graph. First, we compute minimum pendant dominating Estrada index for complete graph, star graph, complete bipartite graph and cocktail party graph which are amongst the most widely-used graph classes. Also, upper and lower bounds for this new index are established. Finally, the rela- tions between the new Estrada index and the new type of energy are investigated.