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이규환,장도연,김동수,Lee, Gyu-Hwan,Jang, Do-Yeon,Kim, Dong-Su 한국기계연구원 1998 硏究論文集 Vol.28 No.-
The corrosion failure analysis for the heating pipeline of apartment was performed. Usually, the heating pipe was layed in the concrete. However, it was known that the corrosion problems could be induced by admixture containing chlorine such as set accelerant. antifreezer and so on. Therefore the new construction method using stone ash instead of concrete was attempt to solve these problems. However water leaking accidents by corrosion occurred after 1 month from the completion of the apartment. In this paper, the reason of corrosion failure was investigated by the field study and laboratory analysis in many aspects.
$Fe^{II}-Co^{III}$이핵착물의 광유발 전자이동반응
이규환,Lee, Gyu Hwan 대한화학회 1994 대한화학회지 Vol.38 No.8
이핵착물 $(NC)_5FeII-L-CoIII(NH_3)_5$ 분자내에서의 광유발 전자이동반응을 정류상태 광분해 실험으로 조사하여 속도상수를 결정하고 다리리간드 L의 종류에 따른 영향을 고찰하였다. 금속 결합자리 사이에 콘쥬게이션이 유지되는 BP, PHEN, DAP 리간드는 klight가 약 $3{\times}10^{-2} sec^{-1}$, 양자수율이 상한값인 1이였으며 콘쥬게이션이 유지되지 못하는 BPEA리간드인 klight가 약 $2{\times}10^{-4} sec^{-1}$, 양자수율이 0.03으로 측정되었다. 이로부터 광유발 전자이동반응이 전하이동 들뜬 상태 MLCT*를 거치는 "화학적 메카니즘"인 것으로 증명하였다. Light-induced electron transfer reaction within binuclear complex $(NC)_5FeII-L-CoIII(NH_3)_5$ was studied with steady-state photolysis and the rate constants were measured for various bridging lignands. klight and quantum yields for BP, PHEN, DAP having conjugation between metal binding sites were about $3{\times}10^{-2} sec^{-1}$ and 1, and for BPEA having no conjugation were about $2{\times}10^{-4} sec^{-1}$ and 0.03. Light-induced electron transfer reaction within binuclear complex was proved to be the chemical mechanism which had charge transfer excited state MLCT*.