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메틸 2-클로로-2-(메틸티오)아세트산을 이용한 치환페놀류로부터 2(3H)-벤조푸란온 유도체의 합성
최홍대(Hong Dae Choi),김미헌(Mi Heun Kim),신상훈(Sang Hoon Shin),손병화(Byung Wha Son) 대한약학회 1996 약학회지 Vol.40 No.6
5-Alkyl-2(3H)-benzofuranones(3a-e) were prepared from Friedel-Crafts reaction of 4-alkylphenols with methyl 2-chloro-2-(methylthio)acetae(1) followed by the treatment of zinc dust-acetic acid. The reaction of disubstituted phenols with 1 in the presence of stannic chloride afforded 3-methyltWa-2(3H)-benzofuranone derivatives(11a-c), which were readily converted into 2(3H)-benzofuranone derivatives(12a-c) by desulfurization with zinc dust-acetic acid.
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중국 정부의 ‘和諧’(조화) 정책에 대한 수사학적 분석
나민구(Na, Mingu),김미헌(Kim, Miheon) 한국수사학회 2016 수사학 Vol.0 No.25
The harmony society supports the improvement of all the people’s condition in China by radically solving many kinds of imbalance based on the idea of 以民爲本(Yi min wei ben)people are the basis of a nation). Not surprisingly, the Chinese people may have hoped for a better environment through the political slogan by the Hu Jintao Government. But contrary to their expectations, the government suppressed press and tightened the Internet censorship, which raised an anti-government sentiment. In return, the people used the negative slang ‘被和諧’(bei hexie, passive harmony or disharmony) as an expression of their protest at the policy, which represents the ridicule on the Chinese phenomenon deviant from the original intention of a harmonious society. So Xi Jinping, the fifth-generation leader drastically reduced usage count of the slogan(harmony or harmony society) in all sorts of political official papers and the press. The Xi Jinping Government didn’t give up the harmony society, but the government judged more appearance of the slogan would increase the anti-government sentiment. The government has tried to solve more fundamental problems of the angry people and conducted anti-corruption movement in their government, which has showed a successful result until now. It is required that the people should watch the effort of the Xi Jinping Government who tries to restore the original intention of the harmony policy which has been deviated from the beginning.
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중학생의 심리적 안녕감과 자기주도학습 능력의 관계에서 내재적 학습동기와 진로성숙도의 매개효과
이유경(Lee, Yu-gyeong),최윤정(Choi, Yoon-jung),김미헌(Kim, Mi-hun) 한국교육상담학회 2021 교육상담연구 Vol.2 No.2
본 연구는 중학생의 심리적 안녕감이 자기주도학습 능력에 정적인 영향을 미치는 관계에서 진로성숙도와 내재적 학습동기의 매개효과를 살펴보았다. 이를 위해 본 연구는 K지역 내 W시에 거주하는 남·여 중학교 3학년 학생 373명을 대상으로 심리적 안녕감 척도, 자기주도학습 능력 척도, 진로성숙도 척도와 내재적 학습동기 척도를 측정하였다. 수집된 자료를 활용하여, 기술통계, 상관분석을 실시했으며, Hayes(2013)의 PROCESS Macro model 4를 이용하여 회귀분석을 통해 매개효과를 검증하였다. 연구결과 첫째, 심리적 안녕감, 진로성숙도, 내재적 학습동기와 자기주도학습 능력의 주요 변인들 간 유의한 정적상관이 나타났다. 둘째, 심리적 안녕감이 자기주도학습 능력에 정적인 영향을 미칠 때, 내재적 학습동기는 부분 매개효과가 있는 것으로 나타나 심리적 안녕감이 자기주도 학습능력을 향상시키는 과정에서 내재적 동기가 부분적으로 그 원인이 될 수 있음을 확인하였다. 이러한 연구결과를 바탕으로 중학생의 인성과 학업 및 진로 발달을 촉진하기 위한 학교상담과 생활지도에서 진로성숙도와 내재적 학습동기의 향상을 위한 개입에 대한 시사점을 제공하였다. This study examined the mediating effect of career maturity and intrinsic learning motivation in a relationship in which the psychological well-being of middle school students positively affects self-directed learning ability. To this end, this study measured psychological well-being scale, self-directed learning ability scale, career maturity scale, and intrinsic learning motivation scale for 373 third-year male and female middle school students living in W city in K region. Descriptive statistics and correlation analysis were conducted using the collected data, and the mediating effect was verified through regression analysis using Hayes (2013) PROCESS Macro model 4. As a result of the study, first, there was a significant positive correlation between the main variables of psychological well-being, career maturity, intrinsic learning motivation, and self-directed learning ability. Second, when psychological well-being has a positive effect on self-directed learning ability, intrinsic learning motivation appears to have a partial mediating effect, confirming that intrinsic motivation can partially be the cause in the process of improving self-directed learning attitude. Based on these research results, implications for intervention to improve career maturity and intrinsic learning motivation in school counseling and life guidance to promote personality, academic and career development of middle school students were provided.
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메틸 2-클로로-2-(메틸티오)아세트산을 이용한 치환페놀류로부터 2(3H)-벤조푸란온 유도체의 합성
최홍대,김미헌,신상훈,손병화 동의대학교 기초과학연구소 1997 基礎科學硏究論文集 Vol.7 No.1
5-Alkyl-2(3H)-benzofuranones(3a-e) were prepared from Friedel-Crafts reaction of 4-alkyl-phenols with methyl 2-chloro-2-(methylthio)acetate(1) followed by the treatment of zinc dust-acetic acid. The reaction of disubstituted phenols with 1 in the presence of stannic chloride afforded 3-methylthio-2(3H)-benzofuranone derivatives(11a-c), which were readily converted into 2(3H)-benzofuranone derivatives(12a-c) by desulfurization with zinc dust-acetic acid.
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