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Zuojun Wei,Yuran Cheng,Mengting Chen,Yuhua Ye,Yingxin Liu 한국화학공학회 2022 Korean Journal of Chemical Engineering Vol.39 No.7
Using nitrogen-doped mesoporous carbon (NMC) as the support, several NiRe bimetallic catalysts withlow metal loading of 1 wt% were designed and prepared for the selective deoxygenation of oleic acid to n-heptadecanein the absence of hydrogen. Results showed that the Ni80Re20/NMC catalyst with a Ni/Re molar ratio of 80 : 20 achievedthe highest yield of n-heptadecane (92.3%) at 330 oC for 2 h in isopropanol solvent, and at a metal/oleic acid weightratio of 1 : 333. The catalyst can be reused at least five times with slight activity loss. Combined with the results of insituXRD, HRTEM, XPS and CO2-TPD, the formation of NiRe alloy, the very fine NiRe nanoparticle size at 2.30 nm, aswell as the hydrophobic, mesoporous and weakly basic properties of the NMC support surface were demonstrated tocontribute to the excellent catalytic performance of the catalyst.