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Tong Li,Xuelian Ba,Xiuju Wang,Zhongpeng Wang,Jie Yang,Yu Cui,Liguo Wang 대한환경공학회 2023 Environmental Engineering Research Vol.28 No.1
Forward osmosis (FO) membrane is a promising membrane technique. However, its application in desalination is limited. Thus, we synthesized MIL-53(Fe)@γ-Al₂O₃ via solvent-thermal method to fabricate MIL-53(Fe)@γ-Al₂O₃/cellulose acetate (CA) composite membranes of high desalination performance. MIL-53(Fe)@γ-Al₂O₃ and MIL-53(Fe) particles were studied using XRD, FITR, SEM, N₂ adsorption-desorption isotherms, and AFM. The structural features of MIL-53(Fe)@γ-Al₂O₃/CA membrane and MIL-53(Fe)/CA membrane were analyzed using SEM, AFM and water contact angle. The reverse salt flux and water flux of the MIL-53(Fe)@γ-Al₂O₃/CA membrane reached 1.78 g m<SUP>-2</SUP> h<SUP>-1</SUP> and 37.1 L m<SUP>-2 </SUP>h<SUP>-1</SUP>, respectively, when the deionized water and 1 M NaCl solution were the feed solution and traction solution, respectively. Compared to the MIL-53(Fe)/CA membrane, the MIL-53(Fe)@γ-Al₂O₃/CA membrane demonstrated better perviousness and selectivity properties of the membrane. This study shows a potential advantage of MOF composites as additives for improvement in the desalination performance of forward osmosis membranes.
Tong Li,Xuelian Ba,Xiuju Wang,Zhongpeng Wang,Jie Yang,Yu Cui,Liguo Wang 대한환경공학회 2023 Environmental Engineering Research Vol.28 No.1
Forward osmosis (FO) membrane is a promising membrane technique. However, its application in desalination is limited. Thus, we synthesized MIL-53(Fe)@γ-Al2O3 via solvent-thermal method to fabricate MIL-53(Fe)@γ-Al2O3/cellulose acetate (CA) composite membranes of high desalination performance. MIL-53(Fe)@γ-Al2O3 and MIL-53(Fe) particles were studied using XRD, FITR, SEM, N2 adsorption-desorption isotherms, and AFM. The structural features of MIL-53(Fe)@γ-Al2O3/CA membrane and MIL-53(Fe)/CA membrane were analyzed using SEM, AFM and water contact angle. The reverse salt flux and water flux of the MIL-53(Fe)@γ-Al2O3/CA membrane reached 1.78 g m−2 h−1 and 37.1 L m−2 h−1, respectively, when the deionized water and 1 M NaCl solution were the feed solution and traction solution, respectively. Compared to the MIL-53(Fe)/CA membrane, the MIL-53(Fe)@γ-Al2O3/CA membrane demonstrated better perviousness and selectivity properties of the membrane. This study shows a potential advantage of MOF composites as additives for improvement in the desalination performance of forward osmosis membranes.