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Rapid recycling of waste salt core materials in foundry industry using fractional crystallization
Xiaolong Gong,Xiongjie Xiao,Qianqian Li,Jianwei Zhao,Zitian Fan 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.124 No.-
The water-soluble composite salt core materials have attracted increasing interest in the manufacture ofhollow castings with complex structures due to their high strength and excellent water solubility, whilethe treatment of waste brine generated from the salt core represents a major pain point for its large-scaleapplication. To change the above situation, the recycling technology of the waste brine from compositesalt core materials was developed using cooling crystallization combined with solvent-driven crystallization. The influences of dissolution temperature and solvent content on the recovery rate of the compositesalt core materials, including inorganic salt and fortifier, were investigated. In addition, the mechanicalproperties and microstructures of the composite salt core with multiple cycles were compared and analyzed. The results show that the fortifier material of corundum powder exhibits excellent chemical andthermal stability with a 100% recovery rate, and the recovery rate of inorganic salt material can reach79.31% with a 40 C dissolution temperature and a 1.0 mass ratio of methanol to brine. The microstructures,phase compositions and mechanical properties of the multi-recycled composite salt core have notchanged, demonstrating that the recycling of the water-soluble composite salt core is feasible, and favoringthe green development of the foundry industry.
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