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        Microstructure Evolution and Mechanical Performances of SiCf Reinforced (Al3Ti + Al3Ni)-Based Metallic–Intermetallic Laminate Composite

        Yuqiang Han,Qinghua Que,Ran Cheng,Ran Cheng,Chunfa Lin,Wenqing Han,Enhao Wang,Junyi Zhu,Haoran Yan 대한금속·재료학회 2021 METALS AND MATERIALS International Vol.27 No.10

        In present work, a novel SiCfreinforced (Al3Ti + Al3Ni)-based metallic–intermetallic laminate (Ti–(Al3Ti + Al3Ni)/SiCf-MIL) composite without centerline defect was prepared using Ti, Al foils, NiTi wires and SiC fibers by vacuum hot pressingsintering method. Electron backscatter diffraction was employed to characterize the microstructure and phase constituents ofTi–(Al3Ti + Al3Ni)/SiCf-MIL composite during various stages of preparation process. The elimination mechanism of intermetalliccenterline was discussed. Besides, quasi-static compressive performance and fracture toughness of the synthesizedcomposite were investigated. The experimental results indicated that as reaction time increasing, the NiTi/Al interfacialreaction occurred prior to the Ti/Al interfacial reaction to form an Al3Ti/Al3Ni zone. Then, the oxides gathered at the frontof Ti/Al interfacial reaction layer were dispersed in the intermetallic layer rather than being pushed together to generate thecenterline due to the Al3Ti/Al3Ni zone. After reaction, there were no residual NiTi phases and intermetallic layers mainlyconsisting of Al3Tiand Al3Niphases were obtained in this composite. In addition, high angle grain boundaries in Al3Tigrains occupied a large proportion, conversely, low angle grain boundaries dominated in Al3Nigrains. Furthermore, stressconcentration appears at the interface between layers instead of along the middle plane of intermetallic layer. Moreover,both compressive strength and fracture toughness of the composite are superior in comparison with SiCfreinforced Ti–Al3Timetallic–intermetallic laminate composite (Ti–Al3Ti/SiCf-MIL) ascribed to the elimination of centerline.

      • KCI등재

        Pediatric Spinal Hemangioblastomas: Clinical Features and Surgical Outcomes of 39 Cases

        Bo Han,Liang Zhang,Wenqing Jia 대한척추신경외과학회 2023 Neurospine Vol.20 No.1

        Objective: Spinal hemangioblastomas (HBs) are a rare pathology, especially in the pediatric population. The natural history and long-term outcomes of pediatric patients with spinal HBs remain unclear due to their scarcity. Methods: A retrospective review of the clinical data and treatment outcomes of children with spinal HBs in our institution from 2012 to 2021 was conducted. Results: Thirty-nine pediatric patients were included, with an average age of 15.9 ± 2.9 years (range, 8–18 years), and 51.3% were female. Children were more likely to have von Hippel-Lindau (VHL) disease (p < 0.001), a family history of VHL (p < 0.001), multiple symptoms (p = 0.006), a shorter duration of symptoms (p < 0.001), and a larger lesion size (p = 0.004) and volume (p = 0.008) than their adult counterparts. The VHL-associated group of patients was more likely to present with multiple symptoms (p = 0.026), have a family history of VHL (p < 0.001), have multiple HBs (p < 0.001) and have synchronous intracranial lesions (p < 0.001) than the sporadic group. After surgery, 15 patients (38.5%) showed improved clinical outcomes, 17 patients (43.6%) remained unchanged, 4 patients (10.2%) worsened, and 3 patients (7.7%) died of tumor progression. During follow-up, there was a high rate of recurrence and repeated surgery, especially for children in the VHL-associated group. Conclusion: Pediatric patients with spinal HBs appear to have a higher relapse risk than their adult counterparts. Therefore, life-long follow-up of these patients is necessary, especially for VHL-associated cases. Surgery can benefit children with HBs and should be considered early to avoid irreversible neurological deterioration.

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        Recovery of zinc and iron from high iron-bearing zinc calcine by selective reduction roasting

        Junwei Han,Wei Liu,Wenqing Qin,Bing Peng,Kang Yang,Yongxing Zheng 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.22 No.-

        A novel method to recover zinc and iron from high iron-bearing zinc calcine by reduction roasting-lowacid leaching-magnetic separation was proposed. The effects of roasting and leaching conditions wereinvestigated and their optimum conditions were established. Meanwhile, the mineralogical changesduring the processes were characterized by XRD, VSM, SEM and LPSA. The results show the ZnFe2O4 inthe calcine was decomposed into ZnO and Fe3O4, and about 92.6% Zn was extracted from the roastedcalcine with reporting most of iron as magnetite into the residue. Finally, more than 90% Fe wasrecovered from the residue by magnetic separation method.

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