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        Sex does not clinically influence the functional outcome of total knee arthroplasty but females have a lower rate of satisfaction with pain relief

        Clement N. D.,Weir D.,Holland J.,Deehan D. J. 대한슬관절학회 2020 대한슬관절학회지 Vol.32 No.-

        Background: The aims were to assess whether sex had a clinically significant independent influence on the outcome of total knee arthroplasty (TKA) according to the Western Ontario and McMaster Universities Osteoarthritis Index (WOMAC) score, Short Form (SF-) 12 scores and patient satisfaction at 1 year. Methods: A retrospective cohort of 3510 primary TKA were identified. Patient demographics, comorbidities, WOMAC and SF-12 scores were collected preoperatively and 1 year postoperatively. Patient satisfaction were assessed at 1 year. Results: There were 1584 males and 1926 females. The preoperative WOMAC and SF-12 scores were significantly (p < 0.001) worse in females but were not greater than the minimal clinically important difference (MCID). When adjustments had been made for confounding differences, females showed a significantly greater improvement in their function (1.5 points, p = 0.03) and total (1.5 points, p = 0.03) WOMAC scores compared to males, but these were not greater than the MCID. When adjustments had been made for confounding differences, females were less likely to be satisfied with their pain relief (p = 0.03) relative to males. Conclusion: Sex does not clinically influence the knee specific outcome (WOMAC) or overall generic (SF-12) health 1 year after TKA. However, satisfaction with pain relief after TKA was significantly less likely in female patients.

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        A Soluble ‘Ba(Ni-ett)’ (ett = 1,1,2,2-ethenetetrathiolate) Derived Thermoelectric Material

        Yaoyang Hu,Geoffrey Rivers,Michael P. Weir,David B. Amabilino,Christopher J. Tuck,Ricky D. Wildman,Oleg Makarovsky,Simon Woodward 대한금속·재료학회 2024 ELECTRONIC MATERIALS LETTERS Vol.20 No.2

        We describe the synthesis and characterisation of the fi rst of a new class of soluble ladder oligomeric thermoelectric materialbased on previously unutilised ethene-1,1,2,2-tetrasulfonic acid. Reaction of Ba(OH) 2 and propionic acid at a 1:1 stoichiometryleads to the formation of the previously unrecognised soluble [Ba(OH)(O 2 CEt)] H 2 O. The latter when used to hydrolyse1,3,4,6-tetrathiapentalene-2,5-dione (TPD), in the presence of NiCl 2 , forms a new material whose elemental compositionis in accord with the formula [(EtCO 2 Ba) 4 Ni 8 {(O 3 S) 2 C = C(SO 3 ) 2 } 5 ] 22H 2 O ( 4 ). Compound 4 can be pressed into pellets,drop-cast as DMSO solutions or ink-jet printed (down to sub-mm resolutions). While its room temperature thermoelectricproperties are modest (σ max 0.04 S cm −1 and Seebeck coeffi cient, α max − 25.8 μV K −1 ) we introduce a versatile new oligomericmaterial that opens new possible synthetic routes for n-type thermoelectrics.

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