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Mohamad Nurul Azman Mohammad Taib,Wageeh A. Yehye,Nurhidayatullaili Muhd Julkapli 한국섬유공학회 2019 Fibers and polymers Vol.20 No.1
Nanocellulose antioxidant (Aox-NCC) was used as reinforcement and crosslinking agent in nitrile butadiene rubber (NBR) composites. The crosslinking density and volume of rubber bonded in the matrix were increased up to 3 phr and no significant improvement between 4 phr and 5 phr was recorded. The interactions of gallic acid and NCC was found to occur between the -OH and -COOH groups, as revealed by Fourier Transform Infra-Red (FTIR) and Nuclear Magnetic Resonance (NMR) analysis. Crystallinity index of Aox-NCC was increased more than 11 %, recorded by X-ray diffraction(XRD) analysis. Meanwhile, the thermal stability of Aox-NCC was increased 30 oC, analyzed by thermogravimetry (TG). With the addition of 3 phr Aox-NCC, tensile strength and modulus at 500 % for NBR composites were increased significantly up to 20 %. There was no significant improvement on modulus at 100 %, modulus at 300 %, elongation at break and tear strength. The degradability of NBR composites within 6 months period was improved significantly at 5 phr of Aox-NCC. Increase in carbonyl group after soil burial test with the existence of cracks, voids and degradable parts of NBRcomposites were revealed. This demonstrated that, Aox-NCC plays a secure function to reinforce NBR composites.
Mohamad Nurul Azman Mohammad Taib,Wageeh Abdulhadi Yehye,Nurhidayatullaili Muhd Julkapli,Sharifah Bee O. A. Abdul Hamid 한국섬유공학회 2018 Fibers and polymers Vol.19 No.2
Novel acetylation process by substitution of acetic anhydride substitution with hydroxyl groups on nanocellulose (NCC) has been explored to increase its dispersion and interaction in nitrile butadiene (NBR) matrix. The crystallinity index was increased after modification when compared to unmodified NCC, but no significant different with increases of treatment time from 1 hour to 3 hours treatments proven by X-ray diffraction (XRD) results. The Fourier transform infra-red (FTIR)showed the existent of acetyl groups on surface of the NCC after treatment by existent of the peak 1736 cm-1 that attributed to carbonyl groups some peaks were observed at 1430, 1361 and 1248 cm-1 and confirmed on the acetylation process. The nuclear magnetic resonance (NMR) also show the present of acetyl groups by existent of the signal of proton methyl group at 1.90 ppm and new peaks at 5.42, 4.70 and 4.34 ppm, for all ACN samples. The thermal results by thermo gravimetric analysis (TGA) and differential scanning calorimetry (DSC) showed that the acetylated NCCs were 10 % more thermally stable. Transmission electron microscopic (TEM) results showed that no significant changes were observed due to the acetylation process. The results also showed well distributed of individual NCC after acetylation, this improvement was primarily attributed to uniform dispersion of the ACN-NCC and less aggregated occurred. Due to its hydrophobic characteristics, highly crystalline and nano size, ACN-NCC brought a significant improvement up to 25 % on the mechanical properties of nitrile butadiene (NBR) rubber composites.
Muhammad K. Abdulwahab,Azhar Ariffin,Wageeh A. Yehye,Azlina Abdul-Aziz,Huda S. Kareem,Nurdiana Nordin 대한화학회 2015 Bulletin of the Korean Chemical Society Vol.36 No.11
The synthesis of antioxidant compounds bearing pharmacologically active groups has become a research interest in the last decade. A series of hydrazones containing a butylated hydroxyl group were synthesized from 2-((3,5-di-tert-butyl-4-hydroxybenzyl)thio)acetohydrazide and various benzaldehyde derivatives, and their radical scavenging activity was explored by 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay and computational calculations. Based on the results, the effects of different substituents on the DPPH IC50 values were discussed. The bond dissociation enthalpies (BDE) of OH and NH bonds and the spin density (SD) values of the compounds were calculated using the density functional theory (DFT) to determine the theoretical capability of the hydrazones as radical scavengers. Based on the results, the effects of the thioether group and the substituent groups next to the NH bond on the BDE values were also discussed.
Graphene metal nanocomposites — Recent progress in electrochemical biosensing applications
Ibrahim Khalil,Shahrooz Rahmati,Nurhidayatullaili Muhd Julkapli,Wageeh A. Yehye 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.59 No.-
The integration of metal, metal oxides or metal alloy nanostructures with graphene increases the surface area, active sites for binding analytes, conductivity as well as mechanical strength of the biosensor. Graphene-metallic nanocomposites by their synergistic effect exhibit greater sensitivity for the detection of a variety of biomolecules. Herein, this review addresses the most recent progress on the design and fabrication of graphene metallic nano-biointerfaces in electrochemical biosensing, detection of biomolecules ranging from most common analytes to sophisticated molecules with greater sensitivity as well as good selectivity from the real-time sample in presence of common interfering substances.