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Luka Suhadolnik,Andrej Pohar,Uroš Novak,Blaž Likozar,Aleš Miheli9c,Miran Ceh 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.72 No.-
Reactive Red 106, a synthetic azo dye, was degraded by means of photocatalysis, electrocatalysis andphoto-electrocatalysis with an immobilized titanium dioxide nanotube catalyst. The plannedfirst part ofthe experiments was carried out inside a photo-electrocatalytic continuous-flow microreactor unit,which was used for the evaluation of the effective decomposition mechanisms, the assessment of theinvestigated degradation kinetics and the transport. The processes were described with a convection–diffusion–reaction mathematical model. Full degradation was achieved under photo-electrocatalyticoperation. The second half of the tests was executed inside a batch-vessel system, consisting of twoseparate compartments. In the anode device partition, an electrode, made of a nanometer-scaled TiO2tubefilm, was placed, whereas a Ti foil was positioned in the cathode’s electrical section. The separationof the electrolytes made it possible to analyze the conversion individually, monitoring the disintegrationof the textile pigment compound in each structural component separately, and studying the changingenvironmental phenomena for either the polarized positive or negative function. Water-based producedchemicals were determined with ultra-high-performance liquid chromatography (UHPLC), coupled withultraviolet–visible (UV–vis) or mass (MS) spectroscopy detectors. The solution was successfullydiscolored (100%) either under engineered microfluidic operation or inside a beaker’s enclosed volume. However, the rate inside the latter was faster, while there were unlike intermediate species formed ineither the anodic or cathodic electrochemical cell. The maximum conversion achieved on the anode sidewas 80% of the initial concentration of the dye, whereas 63% of the dye was degraded on the cathode side. Finally, a scaled-up input configuration was designed for treating larger feedstock capacities.
The Iterated Ritz Method: Basis, implementation and further development
Dvornik, Josip,Lazarevic, Damir,Uros, Mario,Novak, Marta Savor Techno-Press 2018 Coupled systems mechanics Vol.7 No.6
The Ritz method is known as very successful strategy for discretizing continuous problems, but it has never been used for solving systems of algebraic equations. The Iterated Ritz Method (IRM) is a novel iterative solver based on the discretized Ritz procedure applied at each iteration step. With an appropriate choice of coordinate vectors, the method may be efficient in linear, nonlinear and optimization problems. Additionally, some iterative methods can be explained as special cases of this approach, which helps to understand advantages and limitations of these methods and gives motivation for their improvement in sense of IRM. In this paper, some ideas for generation of efficient coordinate vectors are presented. The algorithm was developed and tested independently and then implemented into the open source program FEAP. Method has been successfully applied to displacement based (even ill-conditioned) models of structural engineering practice. With this original approach, a new iterative solution strategy has been opened.