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Liu, Tonghuan,Fang, Jian,Zhang, Yaping,Zeng, Zhengzhi The Polymer Society of Korea 2008 Macromolecular Research Vol.16 No.8
A series of pH and temperature-responsive (N,N-diethylacrylamide-co-methylacrylic acid) copolymers were synthesized by radical copolymerization and characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (NMR) $^1H$, $^{13}C$ and LLS. The effects of salt and pH on the phase transition behaviors of the copolymers were investigated by uv. With increasing NaCl concentration, significant salt effects on their phase transition behaviors were observed. UV spectroscopic studies showed that the phase transition became faster with increasing NaCl concentration. In addition, the phase transition behaviors of copolymers were sensitive to pH. The pH and temperature sensitivity of these copolymers would make an interesting drug delivery system.
Yaping Zhang,Jian Fang,Tonghuan Liu,Qiang Wang,Jihua Zhao,Weiguo Shen 한국고분자학회 2012 Macromolecular Research Vol.20 No.5
A series of temperature-sensitive N,N-diethylacrylamide-co-acrylic acid microgels were synthesized by modified surfactant-free emulsion polymerization method and characterized by Fourier transform infrared spectroscopy,turbidimetric method, scanning electron microscopy (SEM), and dynamic light scattering (DLS) measurements. The SEM images showed that the as-synthesized microgels were monodispersed as spherical particles and the average size increased from 200 to 800 nm with the mole fraction of acrylic acid (AA) increasing from 0 to 0.40. Turbidimetric analysis and DLS investigation indicated that the volume phase transition temperature and the swelling ratio of the microgels had an upward trend that was associated with the higher incorporation of AA. Furthermore,horseradish peroxidase (HRP) was successfully immobilized on the microgel with the greatest swelling ratio (the mole fraction of AA equal to 0.40) to obtain an enzyme-microgel complex for the treatment of wastewater polluted by phenolic compounds. The immobilized HRP achieved a high removal efficiency of >96% toward phenol and was more thermostable and more easily stored and reused compared with free HRP.