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$C_{x}F_{y}$ Polymer Film Deposition in rf and dc $C_{7}F_{16}$ Vapor Plasmas
Sakai, Y.,Akazawa, M.,Sakai, Yosuke,Sugawara, H.,Tabata, M.,Lungu, C.P.,Lungu, A.M. The Korean Institute of Electrical and Electronic 2001 Transactions on Electrical and Electronic Material Vol.2 No.1
$C_{x}F_{y}$ polymer film was deposited in rf and dc Fluorinert vapor ($C_{7}F_{16}$) plasmas. In the plasma phase, the spatial distribution of optical emission spectra and the temporal concentration of decomposed species were monitored, and kinetics of the $C_{7}F_{16}$ decomposition process was discussed. Deposition of $C_{x}F_{y}$ film has been tried on substrates of stainless steel, glass, molybdenum and silicon wafers at room temperature in the vapor pressures of 40 and 100 Pa. The films deposited in the rf plasma showed excellent electrical properties as an insulator for multi-layered interconnection of deep-submicron LSI, i.e. the low dielectric constant ∼2.0, the dielectric strength ∼2 MV/cm and the high deposition rate ∼100nm/min at 100W input power.
CYP1A1, GSTM1, GSTT1 and TP53 Polymorphisms and Risk of Gallbladder Cancer in Bolivians
Sakai, Kazuaki,Loza, Ernesto,Roig, Guido Villa-Gomez,Nozaki, Ryoko,Asai, Takao,Ikoma, Toshikazu,Tsuchiya, Yasuo,Kiyohara, Chikako,Yamamoto, Masaharu,Nakamura, Kazutoshi Asian Pacific Journal of Cancer Prevention 2016 Asian Pacific journal of cancer prevention Vol.17 No.2
The Plurinational State of Bolivia (Bolivia) has a high incidence rate of gallbladder cancer (GBC). However, the genetic and environmental risk factors for GBC development are not well understood. We aimed to assess whether or not cytochrome P450 (CYP1A1), glutathione S-transferase mu 1 (GSTM1), theta 1 (GSTT1) and tumor suppressor protein p53 (TP53) genetic polymorphisms modulate GBC susceptibility in Bolivians. This case-control study covered 32 patients with GBC and 86 healthy subjects. GBC was diagnosed on the basis of histological analysis of tissues at the Instituto de Gastroenterologia Boliviano-Japones (IGBJ); the healthy subjects were members of the staff at the IGBJ. Distributions of the CYP1A1 rs1048943 and TP53 rs1042522 polymorphisms were assayed using PCR-restriction fragment length polymorphism assay. GSTM1 and GSTT1 deletion polymorphisms were detected by a multiplex PCR assay. The frequency of the GSTM1 null genotype was significantly higher in GBC patients than in the healthy subjects (odds ratio [OR], 2.35; 95% confidence interval [CI], 1.03-5.37; age-adjusted OR, 3.53; 95% CI, 1.29-9.66; age- and sex-adjusted OR, 3.40; 95% CI, 1.24-9.34). No significant differences were observed in the frequencies of CYP1A1, GSTT1, or TP53 polymorphisms between the two groups. The GSTM1 null genotype was associated with increased GBC risk in Bolivians. Additional studies with larger control and case populations are warranted to confirm the association between the GSTM1 deletion polymorphism and GBC risk suggested in the present study.
Sakai, Koki 한국목재공학회 1992 목재공학 Vol.20 No.3
The application of white-rot fungi to pulping and bleaching processes has been studied at the Wood Chemistry Laboratory in Kyushu University, cooperatively with the Biotechnology Laboratory of Kobe Steel, Ltd. Some successful results of the studies for a biomechanical pulping process, biobleaching of hardwood and softwood kraft pulp, as well as chlorine free biobleaching of oxygen-prebleached hardwood kraft pulp are dealt with. Biological treatment of the pulp bleaching effluent is also described.
POLYMERIC MATERIALS USABLE FOR GAS SENSORS
Sakai, Y. 한국재료학회 1995 Fabrication and Characterization of Advanced Mater Vol.1 No.3
Various types of sensors to monitor humidity and gases were prepared using organic polymers. In order to prepare resistive type humidity sensors which can be used at high humidities, several methods of cross-linking of hydrophilic polymer chains were proposed, while in order to prepare capacitive humidity sensors durable in organic solvent vapors, utilization of cross-linked hydrophobic polymers were proposed. In addition, for a resistive type $CO_2$ sensors, solid polyethylene glycol containing alkali carbonate can be used. Polymers which have dimethyl amino branch can be used for the sorbing layer in a QCM type sensor. These polymers are alos applicable to the fabrication of both resistive and QCM type acetic acid vapor sensor. Polypyrrole and polyaniline can be used to detect $NH_3$gas.