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Dielectric dispersion studies in (C3N2H5)2SbF5
A. Ingram,Z Czapla,S. Wacke 한국물리학회 2016 Current Applied Physics Vol.16 No.3
The dielectric properties of (C3N2H5)2SbF5 were studied in the frequency range of 40 Hz5 MHz and temperature range 343190 K. There are two dispersion ranges. The first one observed in the range of 10 kHz5 MHz and temperature range 300220 K is connected with dipolar relaxation process. The dispersion observed on the crystal plates normal to the a and c crystallographic axes is quite similar. Activation energies connected with dipolar relaxation for both mentioned directions Ed are equal to 0.335 ± 0.020 eV. The second dispersion observed in the frequency range of 40 Hze10 kHz and temperature interval of 343250 K is supposed to be connected with ionic conductivity. Activation energies for the crystal plates normal to the a and c crystallographic axes are close and equal to Ec ¼ 0.50 ± 0.01 eV and Ec ¼ 0.45 ± 0.01 eV, respectively. The dispersion observed on the crystal plate normal to the b axis in the frequency range of 40 He10 kHz and temperature range of 300343 K is connected with supposed ionic conductivity with an activation energy Ec ¼ 0.75 ± 0.02 eV.