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        Characterization of CBD-CdSe1-ySy deposited at low-temperature for photovoltaic applications

        J.I. Contreras-Rascón,J. Díaz-Reyes,J.E. Flores-Mena,M. Galvan-Arellano,L.A. Juárez-Morán,R.S. Castillo-Ojeda 한국물리학회 2015 Current Applied Physics Vol.15 No.12

        We present the structural and optical characterization of cadmium selenide sulphur (CdSe1-ySy) deposited by chemical bath deposition (CBD) technique at low-temperature (20 ± 2 ℃). The sulphur molar fraction is varied from 0 to 42.13%. The chemical stoichiometry is estimated by energy-dispersive X-ray spectroscopy (EDS). The CdSe1-ySy shows hexagonal wurtzite crystalline phase, which was found by X-ray diffraction (XRD) analysis and it was confirmed by Raman spectroscopy. The average grain size of the CdSe1-ySy films was ranged from 1.20 to 1.68 nm that was determined by Debye-Scherrer equation from W(002) direction and it was confirmed by high resolution transmission electron microscopy (HRTEM). This average grain size indicates a high quantum confinement because of it is smaller than the Bohr radii of CdS (2.8 nm) and CdSe (4.9 nm). Raman spectra show two dominant vibrational bands about 208 and 415 cm-1 associated at CdSe-1LO-like and CdSe-2LO-like. By transmittance measurements at room temperature are found that the optical band gap energies vary from 1.86 to 2.16 eV in the range of investigated sulphur molar fraction. Room temperature photoluminescence shows radiative bands in the visible range and a dominant band in the UV range, approximately 3.0 eV, which can be associated with a radiative transition, bound exciton to donor impurity.

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        Mechanosynthesis of graphene nanoribbons from waste zinc–carbon batteries

        Martínez-González J.,Reyes-Contreras D.,Vigueras-Santiago Enrique,Patiño-Carachure C.,Reyes-Esqueda J. A.,Castrejón-Sánchez V. H.,García-Orozco I. 한국탄소학회 2022 Carbon Letters Vol.32 No.2

        The mechanosynthesis route is a physical top–down strategy to produce different nanomaterials. Here, we report the formation of graphene nanoribbons (GNRs) through this route using carbon bars recovered from discarded alkaline batteries as raw material. The mechanosynthesis time (milling time) is shown to have an influence on different features of the GNRs such as their width and edges features. TEM revealed the presence of GNRs with widths of 15.26, 8.8, and 23.55 nm for the milling times of 6, 12, and 18 h, respectively. Additionally, the carbon bars evolved from poorly shaped GNRs for the shortest milling time (6 h) to well-shaped GNRs of oriented sheets forming for the longest milling time. Besides GNRs, graphene sheets (GNS) of different sizes were also observed. The Raman analysis of the 2D bands identified the GNS signal and confirmed the GNRs nature. ID/IG values of 0.21, 0.32, and 0.40 revealed the degree of disorder for each sample. The in-plane sp2 crystallite sizes (La) of graphite decreased to 91, 60, and 48 nm with increasing peeling time. The RBLM band at 288 cm−1 confirmed the formation of the GNRs. Mechanosynthesis is a complex process and the formation of the GNRs is discussed in terms of a mechanical exfoliation, formation of graphene sheets and its fragmentation to reach GNR-like shapes. It is shown that the synthesis of GNRs through the mechanosynthesis route, besides the use of recycled materials, is an alternative for obtaining self-sustaining materials.

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