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      • Effect of Chain Matching between Hydrocarbon and Fatty Acid on High Pressure Rheology

        N. OHNO,R. MUKAI,Md. Z. RAHMAN,K. SHIBATA 한국트라이볼로지학회 2002 한국트라이볼로지학회 학술대회 Vol.2002 No.10

        For estimation of chain-matching phenomena between normal paraffin as a solvent and straight-chain fatty acid as an additive, the density measurement of n-dodecane, n-tetradecane and n-hexadecane were-carried out at oil temperature 313K and pressure up to 1.3 ㎬. Their solidification pressure were easily determined by the appearance of molecular crystal, abrupt volumetric contraction and generation of heat of solidification and showed minima under the matching condition. The bulk modulus K of molecular crystal was evaluated using phase diagram. The bulk modulus showed maxima under the each matching condition. The chain matching effect on the bulk modulus beyond the scope of the interfacial phenomena are confirmed.

      • SCOPUSKCI등재

        Optimal Porous Structure of MnO<sub>2</sub>/C Composites for Supercapacitors

        Iwamura, Shinichiroh,Umezu, Ryotaro,Onishi, Kenta,Mukai, Shin R. Materials Research Society of Korea 2021 한국재료학회지 Vol.31 No.3

        MnO2 can be potentially utilized as an electrode material for redox capacitors. The deposition of MnO2 with poor electrical conductivity onto porous carbons supplies them with additional conductive paths; as a result, the capacitance of the electrical double layer formed on the porous carbon surface can be utilized together with the redox capacitance of MnO2. However, the obtained composites are not generally suitable for industrial production because they require the use of expensive porous carbons and/or inefficient fabrication methods. Thus, to develop an effective preparation procedure of the composite, a suitable structure of porous carbons must be determined. In this study, MnO2/C composites have been prepared from activated carbon gels with various pore sizes, and their electrical properties are investigated via cyclic voltammetry. In particular, mesoporous carbons with a pore size of around 20 nm form a composite with a relatively low capacitance (98 F/g-composite) and poor rate performance despite the moderate redox capacitance obtained for MnO2 (313 F/g-MnO2). On the other hand, using macro-porous carbons with a pore size of around 60 nm increases the MnO2 redox capacitance (399 F/g-MnO2) as well as the capacitance and rate performance of the entire material (203 F/g-composite). The obtained results can be used in the industrial manufacturing of MnO2/C composites for supercapacitor electrodes from the commercially available porous carbons.

      • KCI등재

        Tomographic reconstruction of two-dimensional radiated power distribution during impurity injection in KSTAR plasmas using an infrared imaging video bolometer

        장주혁,최원호,B.J. Peterson,D.C. Seo,K. Mukai,R. Sano,S. Oh,S. H. Hong,홍주환,H.Y. Lee 한국물리학회 2018 Current Applied Physics Vol.18 No.4

        Based on the two-dimensional radiation images obtained by an infrared imaging video bolometer (IRVB) with tangential view, the two dimensional radiation profiles of plasmas in KSTAR were reconstructed. The IRVB installed on KSTAR has a tangential view of the plasma, and thus tomographic reconstruction of the raw images of radiation profiles was performed to remove the chord-integration effect by using a tomographic reconstruction code based on the Phillips-Tikhonov algorithm. Phantom reconstruction tests with various synthetic images were carried out to validate the accuracy of the reconstruction results. It is found that hollow radiation phantoms with strong divertor radiation were reconstructed with high accuracy. Furthermore, the effects of the number of channels of the IR camera, and the number of pixels of the plasma and of the IRVB on reconstruction performance are studied with phantom tests. Two-dimensionally reconstructed images of KSTAR plasmas demonstrated that radiation loss at the plasma edge and near the divertor region increased significantly after gaseous impurity injection. The total radiated power was up to 1.2MWat the disruption, which was 40% of the NBI power. After argon and krypton gas injection, total radiated power was increased by 325 kW and 180 kW, respectively.

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