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A Donor–Acceptor–Donor Structured Organic Conductor with S···S Chalcogen Bonding
Bai, Monalisa,Thomas, Sajesh P.,Kottokkaran, Ranjith,Nayak, Susanta K.,Ramamurthy, Praveen C.,Guru Row, T. N. American Chemical Society 2014 Crystal Growth & Design Vol.14 No.2
<P>A novel thiophene derivative 7,9-di(thiophen-2-yl)-8<I>H</I>-cyclopenta[a]acenaphthylen-8-one (DTCPA) is shown to exhibit high electrical conductivity (1.97 × 10<SUP>–2</SUP> ± 0.0018 S/cm at RT) in the crystalline state. The material shows two orders of increase in conductivity from normal solid to single crystalline state. The crystal structure has S···S chalcogen bonding, C–H···O hydrogen bonding, and π···π stacking as the major intermolecular interactions. The nature and strength of the S···S interactions in this structure have been evaluated by theoretical charge density analysis, and its contribution to the crystal packing quantified by Hirshfeld surface analysis. Further, thermal and morphological characterizations have been carried out, and the second harmonic generation (SHG) efficiency has been measured using the Kurtz–Perry method.</P><P>A novel donor−acceptor−donor structured material with S···S chalcogen bonding is shown to exhibit high electrical conductivity in the crystalline state. Two different types of intermolecular S···S interactions present in the material are shown to be similar to type I and type II halogen bonds, in terms of charge density distribution.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/cgdefu/2014/cgdefu.2014.14.issue-2/cg401069y/production/images/medium/cg-2013-01069y_0014.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/cg401069y'>ACS Electronic Supporting Info</A></P>
Contactless Stimulation of Multiple Piezoelectric Devices Using Electric Field
Tanaya Nayak,Biswaranjan Swain,Praveen P. Nayak,Satyanarayan Bhuyan 한국전기전자재료학회 2021 Transactions on Electrical and Electronic Material Vol.22 No.3
The contactless energy transmission scheme using parallel-plate capacitor like structure has been explored which provides a platform for energization of multiple piezoelectric (piezo) components. In the proposed method, ac electric fi eld lines produced by copper electrodes penetrate to the piezo components that are coaxially aligned and positioned in-between at certain distance away from each electrode. Consequently, the components are strongly excited at a point where the functioning electric field source frequency alike with the mechanical resonant frequency of the piezo components. The maximum output power corresponding to optimum load and resonant frequency acquired from the contactless energized multi piezo devices is better than that of power obtained from contactless energized single piezo component by this parallel-plate capacitor electric field generator. The testing results reveal the practicability of non contact stimulation/excitation of multi piezo components simultaneously through electric fi eld.