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        The Spatial and Seasonal Variation of Trace Metals in Coastal Seawater and Soft Tissue of Chthamalus montagui around the Northwest Coast of Portugal

        Pedro A. Reis,Maria Antónia Salgado,Vitor Vasconcelos 한국해양과학기술원 2017 Ocean science journal Vol.52 No.2

        Metal concentrations (Cd, Cr, Cu, Fe, Mn and Zn) were determined in seawaters and soft tissues of Chthamalus montagui from the northwest coast of Portugal during the four seasons of 2011. The main objectives of this work were to assess seasonal and spatial variations of metals in order to detect hot spots of contamination, to establish correlations between metals in coastal seawaters and C. montagui and to calculate metal bioaccumulation factors (BAFs) in each season. Metal concentrations in coastal seawaters ranged within Cd: 1.2–35 ng L-1; Cr: 15–87 ng L-1; Mn: 77–1763 ng L-1; Cu: 126–1819 ng L-1; Fe: 430–4048 ng L-1 and Zn: 2889–16867 ng L-1 and in C. montagui ranged for Cd: 0.39–1.98 mg kg-1; Cr: 0.45–3.13 mg kg-1; Cu: 0.93–5.70 mg kg-1; Mn: 2.2– 20.4 mg kg-1; Fe: 135–707 mg kg-1 and Zn: 119–782 mg kg-1. Significant spatial and seasonal variations were found between: (i) metal concentrations in seawaters and C. montagui tissues; (ii) the distribution of metal concentrations in C. montagui tissues were Fe > Zn > Mn > Cu > Cr > Cd and (iii) C. montagui showed higher bioaccumulation factors for Fe and Cd than for Cu, Mn and Zn in all seasons. Regarding the metal concentrations accumulated in C. montagui tissues during each season of 2011, the ecological quality classifications of the NW coast of Portugal varied from “Class I – Unpolluted” to “Class III – Remarkably Polluted”.

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        Adhesion of biofilm, surface characteristics, and mechanical properties of antimicrobial denture base resin

        Ana Beatriz Vilela Teixeira,Mariana Lima da Costa Valente,João Pedro Nunes Sessa,Bruna Gubitoso,Marco Antonio Schiavon,Andréa Cândido dos Reis 대한치과보철학회 2023 The Journal of Advanced Prosthodontics Vol.15 No.2

        PURPOSE. This study incorporated the nanomaterial, nanostructured silver vanadate decorated with silver nanoparticles (AgVO3), into heat-cured resin (HT) at concentrations of 2.5%, 5%, and 10% and compared the adhesion of multispecies biofilms, surface characteristics, and mechanical properties with conventional heat-cured (HT 0%) and printed resins. MATERIALS AND METHODS. AgVO3 was incorporated in mass into HT powder. A denture base resin was used to obtain printed samples. Adhesion of a multispecies biofilm of Candida albicans, Candida glabrata, and Streptococcus mutans was evaluated by colony-forming units per milliliter (CFU/mL) and metabolic activity. Wettability, roughness, and scanning electron microscopy (SEM) were used to assess the physical characteristics of the surface. The mechanical properties of flexural strength and elastic modulus were tested. RESULTS. HT 10%-AgVO3 showed efficacy against S. mutans; however, it favored C. albicans CFU/mL (P < .05). The printed resin showed a higher metabolically active biofilm than HT 0% (P < .05). There was no difference in wettability or roughness between groups (P > .05). Irregularities on the printed resin surface and pores in HT 5%-AgVO3 were observed by SEM. HT 0% showed the highest flexural strength, and the resins incorporated with AgVO3 had the highest elastic modulus (P < .05). CONCLUSION. The incorporation of 10% AgVO3 into heat-cured resin provided antimicrobial activity against S. mutans in a multispecies biofilm did not affect the roughness or wettability but reduced flexural strength and increased elastic modulus. Printed resin showed higher irregularity, an active biofilm, and lower flexural strength and elastic modulus than heat-cured resin. [J Adv Prosthodont 2023;15:80-92]

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