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Continuous O2-CO2 production using a Co-based oxygen carrier in two parallel fixed-bed reactors
Teng Zhang,Ningsheng Cai,Zhenshan Li 한국화학공학회 2009 Korean Journal of Chemical Engineering Vol.26 No.3
Oxygen-enriched carbon dioxide stream with oxygen concentration higher than 20 vol% was produced continuously by using a Co-based oxygen carrier packed in two parallel fixed-bed reactors operated in a cyclic manner. Oxygen was absorbed by the oxygen carrier with air being fed. An oxygen-enriched carbon dioxide stream was obtained when the fixed-bed was regenerated with carbon dioxide as a purge gas. Multiple absorption and desorption cycles indicated that the Co-based oxygen carrier had high cyclic stability. XRD analysis determined the absorbed and desorbed products were Co3O4 and CoO, respectively. The TGA results indicated that Co-based oxygen carrier did not react with NO or SO2 during the desorption stage. This Co-based oxygen carrier offers potential for applications in the O2-CO2 production for the oxy-fuel coal combustion process.
CO2 capture from flue gases using a fluidized bed reactor with limestone
Fan Fang,Zhen-shan Li,Ningsheng Cai 한국화학공학회 2009 Korean Journal of Chemical Engineering Vol.26 No.5
The CO2 capture from flue gases by a small fluidized bed reactor was experimentally investigated with limestone. The results showed that CO2 in flue gases could be captured by limestone with high efficiency, but the CO2 capture capacity of limestone decayed with the increasing of carbonation/calcination cycles. From a practical point of view, coal may be required to provide the heat for CaCO3 calcination, resulting in some potential effect on the sorbent capacity of CO2 capture. Experiment results indicated that the variation in the capacity of CO2 capture by using a limestone/coal ash mixture with a cyclic number was qualitatively similar to the variation of the capacity of CO2 capture using limestone only. Cyclic stability of limestone only undergoing the kinetically controlled stage in the carbonation process had negligible difference with that of the limestone undergoing both the kinetically controlled stage and the product layer diffusion controlled stage. Based on the experimental data, a model for the high-velocity fluidized bed carbonator that consists of a dense bed zone and a riser zone was developed. The model predicted that high CO2 capture efficiencies (>80%) were achievable for a range of reasonable operating conditions by the high-velocity fluidized bed carbonator in a continuous carbonation and calcination system.