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- 저자 : Naruta, Y. (검색결과 3 건)
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Yasufumi Katanasaka,Naoki Yoshida,Hirotaka Naitou,Ryuya Naruta,Yusuke Miyazaki,Yoichi Sunagawa,Masafumi Funamoto,Kana Shimizu,Satoshi Shimizu,Numila Sari,Hajime Yamakage,Noriko Satoh-Asahara,Koji Hase 한국식품영양과학회 2021 Journal of medicinal food Vol.24 No.11
Black tea is a popular beverage worldwide. Theaflavins (TFs), which are active functional components of black tea, are potentially valuable for preventing and/or treating the progression of periodontal diseases. Our previous pilot study showed that TF intake decreases the number of Porphyromonas gingivalis (P. gingivalis) bacteria in the saliva. In this study, we aimed to determine whether TF intake improves periodontal disease attributed to oral bacteria in a randomized, placebo-controlled, and double-blind study. A total of 56 healthy subjects without periodontal diseases were enrolled and assigned to the placebo and TF groups (n = 28). TF intake for 6 weeks did not significantly alter the clinical evaluation of subjects. There was no significant adverse effect among the subjects. The number of P. gingivalis and Fusobacterium nucleatum (F. nucleatum) bacteria, which was the primary endpoint in this study, was not impacted by TF intake. The change ratio of Prevotella intermedia was significantly decreased by TF intake (P = .043) when compared with the placebo group. Collectively, our findings suggest that TFs have beneficial effects on oral bacteria for the prevention of periodontal disease. The study protocol was registered in the University Hospital Medical Information Network (UMIN000020049).
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Liu, Bo,Liu, Qingbin,You, Dan,Li, Xiaoyan,Naruta, Yoshinori,Zhu, Weihong The Royal Society of Chemistry 2012 Journal of materials chemistry Vol.22 No.26
<P>The increasing electron-donating ability of the donor part is focused to further optimize the light-harvesting capability. Our strategy is to introduce an additional donor group into the indoline unit in the donor part to form a donor–donor structure (D–D moiety). Three different units (carbazole, fluorene and 4-methylphenyl groups) with different degrees of electron-donating capability are incorporated, thus constructing the specific donor–donor–π–acceptor (D–D–π–A) system (C-CA, F-CA and I-3) and giving a systematic view of the absorption evolution. Through molecular engineering, their light-harvesting capabilities, energy levels and photovoltaic performances were studied. As expected, utilizing strong electron-donating carbazole unit as additional donor, the IPCE spectrum of DSSC based on C-CA is successfully broadened to NIR region on the premise of suitable LUMO level, with an extraordinarily high plateau in visible region till around 700 nm. In the system of C-CA and F-CA, the introduction of <I>n</I>-pentyl group in donor part of carbazole and fluorene unit has little effect on preventing the molecular π-aggregation due to the good co-planarity of π-linker (vinyl thiophene), suggesting that the most effective way to prevent π-aggregation is still the incorporation of long alkyl groups into planar π-linker segment. However, the introducing long alkyl group can effectively prevent the electron recombination between electrons in conduction band (CB) of TiO<SUB>2</SUB> and I<SUB>3</SUB><SUP>−</SUP> ions. Along with the preferable light-harvesting capability, C-CA presents excellent IPCE performance with a short-circuit photocurrent (<I>J</I><SUB>sc</SUB>) of 18.53 mA cm<SUP>−2</SUP>, an open-circuit photovoltage (<I>V</I><SUB>oc</SUB>) of 649 mV, a fill factor of 0.71, corresponding to a power conversion efficiency (<I>η</I>) of 8.49%. The internal relations between chemical structure and conversion efficiency provide a strategy for developing highly efficient organic sensitizers working in whole visible region with high photovoltaic performance.</P> <P>Graphic Abstract</P><P>Utilizing a carbazole unit as additional donor, the photoresponse of C-CA is broadened to the NIR region with a <I>η</I> of 8.49%. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c2jm31704d'> </P>
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