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Cos¸ kun O¨ zdemir,S¸ erife Sac¸macı,SenolKartal,Mustafa Sac¸macı 한국공업화학회 2014 Journal of Industrial and Engineering Chemistry Vol.20 No.6
A new dispersive liquid–liquid microextraction (DLLME) method is proposed for rapid separation,simultaneous extraction and preconcentration of gold and palladium at ultra trace amounts. Theextraction of the analytes was performed in the presence of 5-[(E)-(2,6-diaminopyridine-3-yl)diazenyl]-1,3,4-thiadiazole-2-thiol (DAT) as chelating agent. Chloroform and acetone were used as extraction anddispersive solvents, respectively. The variables affecting the complexation and extraction conditionswere optimized. The calibration curves were linear in the range of 1.1–85 and 0.9–124 mg L-1 with thedetection limits of 0.4 and 0.6 mg L-1, and with the enrichment factors of 94 and 113 for Au and Pd,respectively. The precision (RSD%) was better than 2.4%. The accuracy of the method was verified byanalysing the certified standard reference material (CDN–PGMS-10). The results show that thedispersive liquid–liquid microextraction pretreatment is a sensitive, rapid, simple and safe method forthe separation/preconcentration of gold and palladium.