Nanostructured Bulk Ceramics (Part I)

Han, Young-Hwan,Mukherjee, Amiya K. The Korean Ceramic Society 2009 한국세라믹학회지 Vol.46 No.3

The processing and characterization of ceramic nanocomposites, which produce bulk nanostructures with attractive mechanical properties, have been emphasized and introduced at Prof. Mukherjee's Lab at UC Davis. The following subjects will be introduced in detail in Part II, III, and IV. In Part II, the paper will describe a three-phase alumina-based nanoceramic composite demonstrating superplasticity at a surprisingly lower temperature and higher strain rate. The next part will show that an alumina-carbon nanotube-niobium nanocomposite produced fracture toughness values that are three times higher than that of pure nanocrystalline alumina. It was possible to take advantage of both fiber-toughening and ductile-metal toughening in this investigation. In the fourth section, discussed will be a silicon-nitride/silicon-carbide nanocomposite, produced by pyrolysis of liquid polymer precursors, demonstrating one of the lowest creep rates reported so far in ceramics at the comparable temperature of $1400^{\circ}C$. This was first achieved by avoiding the oxynitride glass phase at the intergrain boundaries. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method. This allowed the sintering to be completed at significantly lower temperatures and during much shorter times. These improvements in mechanical properties will be discussed in the context of the results from the microstructural investigations.

Nanostructured Bulk Ceramics (Part Ⅰ)

한영환,Amiya K. Mukherjee 한국세라믹학회 2009 한국세라믹학회지 Vol.46 No.3

The processing and characterization of ceramic nanocomposites, which produce bulk nanostructures with attractive mechanical properties, have been emphasized and introduced at Prof. Mukherjee’s Lab at UC Davis. The following subjects will be introduced in detail in Part ⅡI, Ⅲ, and Ⅳ. In Part Ⅱ, the paper will describe a three-phase alumina-based nanoceramic composite demonstrating superplasticity at a surprisingly lower temperature and higher strain rate. The next part will show that an alumina-carbon nanotube-niobium nanocomposite produced fracture toughness values that are three times higher than that of pure nanocrystalline alumina. It was possible to take advantage of both fiber-toughening and ductile-metal toughening in this investigation. In the fourth section, discussed will be a silicon-nitride/silicon-carbide nanocomposite, produced by pyrolysis of liquid polymer precursors, demonstrating one of the lowest creep rates reported so far in ceramics at the comparable temperature of 1400℃ This was first achieved by avoiding the oxynitride glass phase at the intergrain boundaries. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method. This allowed the sintering to be completed at significantly lower temperatures and during much shorter times. These improvements in mechanical properties will be discussed in the context of the results from the microstructural investigations. The processing and characterization of ceramic nanocomposites, which produce bulk nanostructures with attractive mechanical properties, have been emphasized and introduced at Prof. Mukherjee’s Lab at UC Davis. The following subjects will be introduced in detail in Part ⅡI, Ⅲ, and Ⅳ. In Part Ⅱ, the paper will describe a three-phase alumina-based nanoceramic composite demonstrating superplasticity at a surprisingly lower temperature and higher strain rate. The next part will show that an alumina-carbon nanotube-niobium nanocomposite produced fracture toughness values that are three times higher than that of pure nanocrystalline alumina. It was possible to take advantage of both fiber-toughening and ductile-metal toughening in this investigation. In the fourth section, discussed will be a silicon-nitride/silicon-carbide nanocomposite, produced by pyrolysis of liquid polymer precursors, demonstrating one of the lowest creep rates reported so far in ceramics at the comparable temperature of 1400℃ This was first achieved by avoiding the oxynitride glass phase at the intergrain boundaries. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method. This allowed the sintering to be completed at significantly lower temperatures and during much shorter times. These improvements in mechanical properties will be discussed in the context of the results from the microstructural investigations.

Tribute Issue: Remembering Ji-Hyung Cho

MUKHERJEE, Rila The Asian Association of World Historians 2015 The Asian review of world histories Vol.3 No.2

The Indian Ocean: Historians Writing History

Mukherjee, Rila The Asian Association of World Historians 2013 The Asian review of world histories Vol.1 No.2

Jatropha curcas: a review on biotechnological status and challenges

Mukherjee, Priyanka,Varshney, Alok,Johnson, T. Sudhakar,Jha, Timir Baran The Korean Society of Plant Biotechnology 2011 Plant biotechnology reports Vol.5 No.3

Plant tissue culture and molecular biology techniques are powerful tools of biotechnology that can complement conventional breeding, expedite crop improvement and meet the demand for availability of uniform clones in large numbers. Jatropha curcas Linn., a non-edible, eco-friendly, non-toxic, biodegradable fuel-producing plant has attracted worldwide attention as an alternate sustainable energy source for the future. This review presents a consolidated account of biotechnological interventions made in J. curcas over the decades and focuses on contemporary information and trends of future research.

Construction of bivariate asymmetric copulas

Mukherjee, Saikat,Lee, Youngsaeng,Kim, Jong-Min,Jang, Jun,Park, Jeong-Soo The Korean Statistical Society 2018 Communications for statistical applications and me Vol.25 No.2

Copulas are a tool for constructing multivariate distributions and formalizing the dependence structure between random variables. From copula literature review, there are a few asymmetric copulas available so far while data collected from the real world often exhibit asymmetric nature. This necessitates developing asymmetric copulas. In this study, we discuss a method to construct a new class of bivariate asymmetric copulas based on products of symmetric (sometimes asymmetric) copulas with powered arguments in order to determine if the proposed construction can offer an added value for modeling asymmetric bivariate data. With these newly constructed copulas, we investigate dependence properties and measure of association between random variables. In addition, the test of symmetry of data and the estimation of hyper-parameters by the maximum likelihood method are discussed. With two real example such as car rental data and economic indicators data, we perform the goodness-of-fit test of our proposed asymmetric copulas. For these data, some of the proposed models turned out to be successful whereas the existing copulas were mostly unsuccessful. The method of presented here can be useful in fields such as finance, climate and social science.

Organic phototransistors based on solution grown, ordered single crystalline arrays of a π-conjugated molecule

Mukherjee, Biswanath,Sim, Kyoseung,Shin, Tae Joo,Lee, Junghyun,Mukherjee, Moumita,Ree, Moonhor,Pyo, Seungmoon The Royal Society of Chemistry 2012 Journal of materials chemistry Vol.22 No.7

<P>High quality, single crystalline, ordered arrays of a π-conjugated organic molecule, <I>N,N′</I>-dioctyl-3,4,9,10-perylene tetracarboxylic diimide (PTCDI-C<SUB>8</SUB>), were grown by solution processing and used to fabricate a low-cost, high-performance organic phototransistor (OPT). The single crystalline nature of the microstructure was investigated using 2D-GIXD measurement. The organic field-effect transistor fabricated using periodic arrays of elongated crystals exhibited a photoresponsivity (<I>P</I>) of <I>ca.</I> 1 A W<SUP>−1</SUP> and a photo to dark current ratio (<I>I</I><SUB>on</SUB>/<I>I</I><SUB>off</SUB>) of 2.5 × 10<SUP>3</SUP> at <I>V</I><SUB>G</SUB> = 12 V and a maximum <I>P</I> of <I>ca.</I> 7 A W<SUP>−1</SUP> at the high gate bias regime (<I>V</I><SUB>G</SUB> = 50 V) with an optical power of <I>ca.</I> 7.5 mW cm<SUP>−2</SUP>. With polymeric gate dielectric, the OPT exhibited very stable n-type characteristics both in the dark and under light illumination and showed reproducible photo-switching behavior. The dependence of the photocurrent on the gate/drain voltage and on illumination intensity provided an effective way to control the number of photo-carriers generated in the active material, enabling the precise tuning of the device's performance. Performance comparison between OPTs with ordered crystal arrays and thin films of PTCDI-C<SUB>8</SUB> confirmed that the material's intrinsic properties were better realized in the crystalline device, presumably because of higher charge carrier mobility and better charge transport capability. This one-step, solution-based, self-assembly fabrication of multifunctional (photodetection, photoswitching, signal amplification) optoelectronic devices has potential to aid the development of organic semiconductors with high-quality micro/nanostructures for large-scale application and low-cost optoelectronic devices.</P> <P>Graphic Abstract</P><P>An organic phototransistor (OPT) was fabricated using solution grown, periodic arrays of PTCDI-C<SUB>8</SUB> single crystals. The OPT exhibited high photosensitivity (7 A W<SUP>−1</SUP>), high on/off current ratio (2.5 × 10<SUP>3</SUP>) and reproducible photo-switching at low optical power. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c2jm14179e'> </P>

Emergence of a novel optically isotropic transient state with low frequency in a blue phase liquid crystal mixture

Mukherjee, A.,Yang, G. H.,Jeong, H.,Nayek, P.,Kang, S. W.,Lee, S. H.,Hong, S. H.,Lee, H. J.,Shin, S. T. Taylor Francis 2012 Liquid crystals Vol.39 No.2

Rate Enhancement by Micelle Encapsulation for Oxidation of L-Glutamic Acid in Aqueous Media at Room Temperature

Mukherjee, Kakali,Saha, Bidyut Korean Chemical Society 2013 대한화학회지 Vol.57 No.4

Oxidation of glutamic acid is performed in aqueous acid media at $30^{\circ}C$ under the kinetic condition [glutamic acid]$_T{\gg}[Cr(VI)]_T$. Effect of combination of micellar catalyst (SDS, TX-100) and promoter (PA, bpy, phen) has been studied. Among the promoters phen accelerates the reaction most in aqueous media. But the rate acceleration is small in the case. Combination of promoter and catalyst produces much better result. Maximum rate enhancement occurs in presence of the combination of bpy and SDS.

Control over Multifunctionality in Optoelectronic Device Based on Organic Phototransistor

Mukherjee, Biswanath,Mukherjee, Moumita,Choi, Youngill,Pyo, Seungmoon American Chemical Society 2010 ACS APPLIED MATERIALS & INTERFACES Vol.2 No.6

<P>Highly stable, reproducible, photosensitive organic field-effect transistors based on an <I>n</I>-type organic material, copper hexadecafluorophthalocyanine, and two different polymeric gate dielectrics has been reported and their performances have been compared by evaluating the surface/interface properties. The devices produced a maximum photocurrent gain (<I>I</I><SUB>light</SUB><I>/I</I><SUB>dark</SUB>) of 79 at <I>V</I><SUB>G</SUB> = 7 V and showed the potentiality as multifunctional optoelectronic switching applications depending upon the external pulses. The switching time of the transistor upon irradiation of light pulse, i.e., the photoswitching time of the device, was measured to be ∼10 ms. On the basis of optical or combination of optical and electrical pulses, the electronic/optoelectronic properties of the device can be tuned efficiently. The multifunctions achieved by the single device can ensure very promising material for high density RAM and other optoelectronic applications. Furthermore, as the device geometry in the present work is not limited to rigid substrate only, it will lead to the development of flexible organic optoelectronic switch compatible with plastic substrates.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/aamick/2010/aamick.2010.2.issue-6/am100127q/production/images/medium/am-2010-00127q_0001.gif'></P>