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Possible degradation pathways of triclosan from aqueous systems via TiO2 assisted photocatalyis
Lucian Alexandru Constantin,Ines Nitoi,Nicolae Ionut Cristea,Mirela Alina Constantin 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.58 No.-
Triclosan (TCS) is an antimicrobial agent used for personal care products that cannot be removed bywastewater treatment classical processes. TCS persistence and toxicity is asking for alternative treatmentmethods such as TiO2 assisted photocatalyse. Due to the fact that within the literature are presentedvarious pathways for TCS degradation via UV/TiO2 photocatalysis, some data being contradictory,research work aimed to propose a degradation mechanism supported by as many experimental data. TCSdegradation pathways confirmed by experimental results were: addition of hydroxyl radicals at TCS nonphenolicring, proton extraction by hydroxyl radicals and direct interaction with photo generatedelectrons.