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        The Effect of H2O2/Fe2+ Catalytic Oxidation System on the Morphology, Structure and Properties of Flake-Like Poly(2,3-dimethylaniline)

        Jun Yan,Li Ma,Mengyu Gan,Xiao Li,Zhitao Li,Jihai Tang,Ying Tu,Haifeng Hu 한국고분자학회 2014 Macromolecular Research Vol.22 No.8

        In this work, flake-like poly(2,3-dimethylaniline) (P(2,3-DMA)) with enhanced thermal stability andanticorrosive ability was synthesized by in situ polymerization using H2O2/Fe2+ catalytic oxidation system, comparingwith traditional oxidant ammonium persulfate (APS) synthetic method. The structure and morphology of thesamples were characterized Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD) and field-emissionscanning electron microscope (FESEM). The experimental results demonstrated that using H2O2/Fe2+ catalytic oxidationsystem was more inclined to form the two-dimensional P(2,3-DMA) flakes. The enhancement in thermostabilityand corrosion resistance was attributed to the formation of phenazine-like structures in the polymer chains,which could serve as templates to form the flake-like morphology. In addition, using H2O2/Fe2+ catalytic oxidationsystem is more environmental friendly than the APS method that can avoid ammonium pollution on aquatic life aswell as waters.

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        Facile Synthesis of Ni–Mn Layered Double Hydroxide Nanopetals on 3D Reduced Graphene Oxide/Ni Foam for High-performance Supercapacitors

        Qi Tang,Menghan Ye,Li Ma,Tao Zhou,Mengyu Gan,Fabing Yan 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2020 NANO Vol.15 No.03

        In this work, the Ni–Mn layered double hydroxide (Ni–Mn LDH) nanopetals are fabricated on three-dimensional reduced graphene oxide/Ni foam (RGO/NF) by one-step hydrothermal method, in which the suspension of graphene oxide (GO) is directly reduced by nickel foam (NF) to obtain NF/RGO. The composite, which consists of interconnected Ni–Mn LDH nanopetals, forms a macroporous structure. Such an open space can promote electrolyte dispersion and ion diffusion of active substances, thus enhancing capacitance performance. Remarkable, during crystal growth, RGO can not only provide active sites for Ni–Mn LDH nanopetals, but also effectively connect Ni–Mn LDH nanopetals to NF, further promoting the electrochemical behavior of composite material. Moreover, RGO possess reasonable chemical stability which can improve the mechanical properties of the composite to obtain good stability. The experimental results show that the NF/RGO electrode material with Ni–Mn LDH nanopetals has excellent specific capacitance of 2250 F g -1 at 1 A g -1, good rate performance (the capacitance retention rate is still 64.0% at 10 A g -1) and excellent cycle life (45.1% at 10 A g -1 after 5000 cycles). NR/NM–LDH is used as the positive electrode and activated carbon is used as the negative electrode to assemble the asymmetric supercapacitor, the proper power density and energy density indicates that the NR/NM–LDH composite has great potential as an electrode material for supercapacitors.

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