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      • KCI등재

        Magnetic Powder and Nano-powder Composites for Electrical Converters

        Mazurkiewicz, Marian,Rhee, Chang-Kyu,Weglinski, Bogumil The Korean Powder Metallurgy Institute 2008 한국분말재료학회지 (KPMI) Vol.15 No.4

        On the base of experience in development of Magnetic Powder Composites, and particularly Soft Magnetic Composites, authors are trying to systematize classification and indicate possible development prospective of Magnetic Nanocomposites (MN) technology and their applications in electrical converters. Clear classification and systematization, at an early stage of any materials and technology development, are essential and lead for better understanding and communication between researchers and industry involved. This concern MN as well and it seems to be the right time to make it at present stage of their development. Presented proposal of classification distinguishes various types of MN by their magnetic properties and area of possible applications. It is not a close set of types, and can be extended due to increase of knowledge concern these nanocomposites.

      • KCI등재

        High Pressure Liquid Jet Technology for Nano Particles Production

        Mazurkiewicz, Marian,Rhee, Chang-Kyu,Weglinski, Bogumil The Korean Powder Metallurgy Institute 2008 한국분말재료학회지 (KPMI) Vol.15 No.5

        Principles and historical background of high pressure liquid jet (HPLJ) technology is presented in the paper. This technology can be applied, among others, for production of nano particles. This target can be achieved in various type of disintegration systems developed and designed on the base of this technology. The paper describes principles of two examples of such systems: HPLJ-reactor, called also a linear comminuting system, HPLJ- centrifugal comminuting system, which prototypes have been manufactured. A linear mill, being high energy liquid jet reactor, has been developed and tested for micronization of various types of materials. The results achieved so far, and presented in the paper, show its potential for further improvement toward nano-size particle production. Flexibility of adjustment of the reactors and the mechanism of the process allows for the creation of particles with unprecedented rheology. The reactor can be especially suitable to micronize, mix and densify materials with a wide range of mechanical properties for various industrial needs. Presented prototypes of comminution systems generate interesting potentials toward production of nano particles. Their performance, based on up today research, confirms expected high efficiency of materials disintegration, which opens a new challenge for industrial applications. The paper points out benefits and area of possible applications of presented technology.

      • SCISCIESCOPUS

        Non-covalent functionalization of multi-walled carbon nanotubes with organic aromatic compounds.

        Lemek, Tadeusz,Mazurkiewicz, Jó,zef,Stobinski, Leszek,Lin, Hong Ming,Tomasik, Piotr American Scientific Publishers 2007 Journal of nanoscience and nanotechnology Vol.7 No.9

        <P>Several aromatic compounds derived from benzene by its annelation (naphthalene, anthracene, phenanthrene, pyrene) and exocyclic substitution (e.g., nitrobenzene, dinitrobenzenes, trinitrobenzene, chlorobenzene, N,N-dimethylaniline, and others) and endocyclic substitution (pyridine, quinoline, isoquinoline) efficiently sorbed on multi-walled carbon nanotubes (MWCNTs). Equilibrium constants for the sorption process have been determined. Computations of the energy of formation were performed for surface complexes of those arenes on single-walled carbon nanotubes (SWCNTs). Formation energies of those complexes were correlated against the experimental equilibrium constants. The latter were also correlated against calculated LUMO energy of the arenes. Solely, limited tendencies to the linearity could be observed. The analysis of the results of the correlations indicated that the arenes acting as the charge acceptors formed stronger complexes than arenes with a high electron density in the molecular orbital, for instance, N, N-dimethylaniline. The area of the arene--SWCNT contact was very essential for the complexation. The proximity of the HOMO orbital of SWCNT and LUMO of the arene was another essential factor. Bulky substituents in the arene molecules obscured their efficient contact with SWCNT.</P>

      • KCI등재후보

        Enhanced electrochemical stability of polyaniline in ionic liquids

        P. C. Innis,T. Nguyen,J. Mazurkiewicz,G. G. Wallace,D. MacFarlane 한국물리학회 2004 Current Applied Physics Vol.4 No.2-4

        The electrochemical performance of polyaniline thin films on platinum electrode substrates has been investigated using cyclic voltammetry in two aprotic ionic liquid electrolyte systems, 1-butyl-3-methyl imidazolium hexafluorophosphate (BMI PF6 ) or 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfon)imide (EMI TFSI). Enhanced redox stability of the polyaniline was observed in both electrolyte systems. Initial redox cycles in both ILs exhibited increasing current responses, over the first 10–20 cycles, which was attributed to the electrochemically induced ion exchange processes occurring within polyaniline film. Extended cycling after the redoping process was observed to result in a stable and reversible electrochemistry.

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