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Zhou, Jiwen,Gong, Maozhen,Mariano, Patrick S.,Yoon, Ung-Chan Korean Chemical Society 2008 Bulletin of the Korean Chemical Society Vol.29 No.1
The key step in a strategy for the synthesis of (+)-lactacystin involving photocyclization reaction of a cyclopenta-fused pyridinium salt has been probed by using a model substrate. Observations made in this effort led to the discovery of a highly unusual cascade process that leads to stereoselective formation of an interesting tricyclic carbamate. The results of this study are presented and discussed in the context of a (+)-lactacystin synthetic approach.
Jiwen Zhou,윤웅찬,Maozhen Gong,Patrick S. Mariano* 대한화학회 2008 Bulletin of the Korean Chemical Society Vol.29 No.1
The key step in a strategy for the synthesis of (+)-lactacystin involving photocyclization reaction of a cyclopenta-fused pyridinium salt has been probed by using a model substrate. Observations made in this effort led to the discovery of a highly unusual cascade process that leads to stereoselective formation of an interesting tricyclic carbamate. The results of this study are presented and discussed in the context of a (+)-lactacystin synthetic approach.