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RISS 인기검색어
- 검색키워드
- 저자 : Ma Fangyuan (검색결과 3 건)
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Study on surface physical and chemical mechanism of nanobubble enhanced flotation of fine graphite
Tang Chongliang,Ma Fangyuan,Wu Tingyu,Zhang Di,Wang Ye,Zhao Tonglin,Fan Zhaolin,Liu Xinyue 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.122 No.-
It has been concluded in a recently published investigation that the nanobubble flotation process significantlyreduces the number of fine flake graphite flotation stages and improves the flotation performance. The present study was conducted to explore the mechanisms of surface nanobubbles enhancing flake graphiteflotation by investigating effects of nanobubbles on surface properties of graphite and interactionsbetween particles and bubbles by use of contact angle analyzer, zeta potential analyzer, FourierTransform Infrared Spectroscopy (FTIR), and X-ray Photoelectron Spectroscopy (XPS). The study resultsshow that nanobubbles can improve the surface properties of graphite and enhance the adsorption effectof collector, which increased the contact angle of the graphite surface by 11.93 compared with conventionalflotation. Infrared spectroscopy and potential analysis showed that the nanobubbles could enhancethe hydrophobic attraction and reduce the electrostatic repulsion between the collector and the graphitesurface, which was beneficial to enhance the hydrophobic surface of the graphite and enhance theagglomeration of fine graphite particles. XPS analysis showed that the nanobubbles covered polar hydrophilicgroups (such as CAO, C@O, COOH) on the graphite surface, which enhanced the adsorption of collectorto improve the hydrophobicity of graphite surface.
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Wang, Shuaifei,Li, Fangyuan,Qiao, Ruirui,Hu, Xi,Liao, Hongwei,Chen, Lumin,Wu, Jiahe,Wu, Haibin,Zhao, Meng,Liu, Jianan,Chen, Rui,Ma, Xibo,Kim, Dokyoon,Sun, Jihong,Davis, Thomas P.,Chen, Chunying,Tian, American Chemical Society 2018 ACS NANO Vol.12 No.12
<P>Ferroptosis, an iron-based cell-death pathway, has recently attracted great attention owing to its effectiveness in killing cancer cells. Previous investigations focused on the development of iron-based nanomaterials to induce ferroptosis in cancer cells by the up-regulation of reactive oxygen species (ROS) generated by the well-known Fenton reaction. Herein, we report a ferroptosis-inducing agent based on arginine-rich manganese silicate nanobubbles (AMSNs) that possess highly efficient glutathione (GSH) depletion ability and thereby induce ferroptosis by the inactivation of glutathione-dependent peroxidases 4 (GPX4). The AMSNs were synthesized <I>via</I> a one-pot reaction with arginine (Arg) as the surface ligand for tumor homing. Subsequently, a significant tumor suppression effect can be achieved by GSH depletion-induced ferroptosis. Moreover, the degradation of AMSNs during the GSH depletion contributed to <I>T</I><SUB>1</SUB>-weighted magnetic resonance imaging (MRI) enhancement as well as on-demand chemotherapeutic drug release for synergistic cancer therapy. We anticipate that the GSH-depletion-induced ferroptosis strategy by using manganese-based nanomaterials would provide insights in designing nanomedicines for tumor-targeted theranostics.</P> [FIG OMISSION]</BR>
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Gate-tunable phase transitions in thin flakes of 1T-TaS2.
Yu, Yijun,Yang, Fangyuan,Lu, Xiu Fang,Yan, Ya Jun,Cho, Yong-Heum,Ma, Liguo,Niu, Xiaohai,Kim, Sejoong,Son, Young-Woo,Feng, Donglai,Li, Shiyan,Cheong, Sang-Wook,Chen, Xian Hui,Zhang, Yuanbo Nature Pub. Group 2015 Nature nanotechnology Vol.10 No.3
<P>The ability to tune material properties using gating by electric fields is at the heart of modern electronic technology. It is also a driving force behind recent advances in two-dimensional systems, such as the observation of gate electric-field-induced superconductivity and metal-insulator transitions. Here, we describe an ionic field-effect transistor (termed an iFET), in which gate-controlled Li ion intercalation modulates the material properties of layered crystals of 1T-TaS2. The strong charge doping induced by the tunable ion intercalation alters the energetics of various charge-ordered states in 1T-TaS2 and produces a series of phase transitions in thin-flake samples with reduced dimensionality. We find that the charge-density wave states in 1T-TaS2 collapse in the two-dimensional limit at critical thicknesses. Meanwhile, at low temperatures, the ionic gating induces multiple phase transitions from Mott-insulator to metal in 1T-TaS2 thin flakes, with five orders of magnitude modulation in resistance, and superconductivity emerges in a textured charge-density wave state induced by ionic gating. Our method of gate-controlled intercalation opens up possibilities in searching for novel states of matter in the extreme charge-carrier-concentration limit.</P>
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