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M. Mahmudzadeh,H. Yari,B. Ramezanzadeh,M. Mahdavian 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.78 No.-
Reduction of graphene oxide still is one of discussion subjects in scientific communities. The use of toxicchemicals like hydrazine is a well-known procedure for graphene oxide reduction. In this paper, a newecofriendly, fully scalable, and cheap approach with easy procedure on industrial scale for producingreduced graphene oxide is introduced. The studied method was based on successful reduction ofgraphene oxide by urtica dioica leaves’ extract in 1 h at 90 C. Raman spectroscopy evidenced thesignificant removal of considerable oxygen functional groups in graphene oxide after reduction. Improving corrosion properties by helping the functionalization ability of u. dioica leaves’ extract forsuperior dispersion in polyurethane coatings was studied as well. Electrochemical impedancespectroscopy measurements along with salt spray exposure test revealed the remarkable role ofresultant reduced graphene oxide in protective function of polyurethane coatings before and afteraccelerated weathering condition. Impedance value in low frequency diagrams reveals more than 99%protection efficiency indicating the great role of u. dioica in barrier property of PU coatings afteraccelerated weathering condition.
Enhancement of silane coating protective performance by using a polydimethylsiloxane additive
M. Mahdavian,B. Ramezanzadeh,M. Akbarian,M. Ramezanzadeh,P. Kardar,E. Alibakhshi,S. Farashi 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.55 No.-
This work intends to study the effect of a polydimethylsiloxane additive on the protection performance of a hybrid silane coating on mild steel. Electrochemical impedance spectroscopy, polarization and electrochemical noise measurements and salt spray showed an increase in corrosion resistance of the silane coating in the presence of the additive. Silane films were examined by FTIR, water droplet contact angle, Vickers hardness and SEM. Results showed decrease in crosslinking density in the presence of the additive. Superior corrosion protection in the presence of additive was attributed to the enhanced hydrophobic character and flexibility of the coating.
Corrosion inhibition properties of a green hybrid pigment based on Pr-Urtica Dioica plant extract
M. Motamedi,B. Ramezanzadeh,M. Mahdavian 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.66 No.-
The main aim of this research is studying the corrosion inhibition properties of the combination of praseodymium nitrate (PrN) and Urtica Dioica (UrDi) on mild steel in sodium chloride solution. Fourier transform infrared (FT-IR), ultraviolet-visible (UV-Vis), thermogravimetric analysis/differential thermogravimetry (TGA/DTG) and X-ray photoelectron spectroscopy (XPS) results confirmed complex formation between Pr cations and UrDi (Pr-UrDi). Electrochemical results revealed that the Pr-UrDi hybrid complex had significant influence on the mild steel corrosion protection (by inhibition efficiency of ca. 94%) in NaCl solution.
M. Mehdipour,B. Ramezanzadeh,S.Y. Arman 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.21 No.1
The inhibition action of Aloe Vera leaf extract as environmentally friendly inhibitor for the corrosionprotection of stainless steel in 1 M H2SO4 solution was studied by electrochemical techniques as well asscanning electron microscope. The results of linear polarization and electrochemical impedancespectroscopy proved the effectiveness of Aloe Vera extract as concentration increased. Corrosioninhibition of Aloe extract was also studied by electrochemical noise (EN). Employing EN, differentaspects like transient analysis, noise resistant and characteristic charge were characterized. Moreover, aliterature review of Aloe Vera characterization using high-performance liquid chromatography and GCMSwas carried out.
S.M. Mousavifard,M.M. Attar,P. MalekMohammadi Nouri,B. Ramezanzadeh 한국공업화학회 2013 Journal of Industrial and Engineering Chemistry Vol.19 No.3
The epoxy/polyamide coating was loaded with different pigment mixtures of the zinc phosphate (ZP),zinc aluminum phosphate (ZPA) and zinc aluminum polyphosphate (ZAPP) pigments. The electrochemical impedance spectroscopy (EIS) and salt spray test were used to investigate corrosion inhibition performance of the coatings. The adhesion strengths of the coatings were measured by a pull-off test. Results revealed lower coating pull-off strength loss when the ZPA and ZAPP pigments were used. A significant decrease in number of blisters together with low pull-off strength loss and best corrosion inhibition properties were observed when the mixture of 80:20 of ZAPP:ZPA was used.
M. Izadi,T. Shahrabi,B. Ramezanzadeh 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.57 No.-
This study aims at synthesis and characterization of a Fe3O4 nanoreservoir (Fe3O4-NS) by an ultrasoundassisted route through a layer-by-layer procedure. An active nanoreservoir was obtained throughinclusion of Nettle extract (NE) as a green corrosion inhibitor. A polyelectrolyte layer of polyaniline (PANI)was employed to loading corrosion inhibitor on the Fe3O4 nanoparticles (Fe3O4-NP) and preventing theinhibitor release from Fe3O4-NS before application. Fe3O4-NS was characterized by different analyticaltechniques. Results obtained confirmed that the PANI and NE layers were successfully deposited on theFe3O4-NP. Electrochemical measurements revealed that Fe3O4-NSfilled with NE is an efficient activecorrosion protective system.
M.H. Shahini,Maryam Mousavi,Amir Masoud Arabi,Mohammad Mahdavian,Bahram Ramezanzadeh 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.101 No.-
In this endeavor, ultra-fine Ce oxide QDs were synthesized via an in-situ approach which itself wasdivided into two methods exploited to synthesize QDs on the GO nanosheets. Afterward, the obtainedproduct was loaded into the Epoxy (EP) structure and finally applied on the surface. The results affirmedthe presence of Ce oxide QDs and the quantum confinement effect in both samples. FT-IR analysis confirmedthe presence of different functional groups such as C@C and CAH. UV–Vis outcome showed theinteraction of GO nanosheets and CeO2 QDs. The morphology of the surface, QDs distribution on theGO nanosheets, shape, and particle sizes were explored using FESEM and HR-TEM. Lastly, the corrosionsuppression of different coatings—pure EP, GO-only-containing EP, or EP loaded with quantum-dotsdepositedGO synthesized by two methods—were compared and discussed in detail with the help ofEIS and salt spray methods. The result showed that, in the scratched samples, the maximum Rct of45,080 ohm.cm2 was reached when the QDs-modified GO, attaining via the first method, was employed. The overall result denoted the superior performance of the QDs-modified GO nanosheets embedded inthe EP coating—most specifically the one synthesized with the first method.
N. Naseh,M. Mohseni,B. Ramezanzadeh 한국공업화학회 2014 Journal of Industrial and Engineering Chemistry Vol.20 No.4
The aim of this study is enhancing an automotive clearcoat easy-to-clean property against simulated tree gum (Arabic gum) using hydroxyl-functional silicone polyacrylate additives having different hydroxyl contents. The clearcoat surface, mechanical and chemical properties were studied using a contact angle measuring device, dynamic mechanical thermal analysis (DMTA) and Fourier Transform Infrared spectroscopy (FT-IR) respectively. It was found that additive with lower hydroxyl content gave rise to better easy-to-clean properties of the clearcoat against Arabic gum. This additive also resulted in lower contact angles and higher cross-linking density, tensile stress and work of break of the clearcoat.
F. Shaghayeghi Toosi,M. Shahidzadeh,B. Ramezanzadeh 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.24 No.-
In this study, the effective functionalities obtained from gel point, dynamic mechanical thermal analysis (DMTA) and tensile tests were compared. Three types of hydroxyl-terminated polybutadiene (HTPB) resins with different functionalities were cured with different curing agents. Results revealed that the functionalities obtained from gel point test were not the same as those obtained from tensile test. Also, the HTPB with the lowest effective functionality resulted in the elastomer with the lowest cross-linking density and stress at break. However, the HTPB with the highest effective functionality did not cause the greatest cross-linking density and stress at break.
H. Sheikhy,B. Ramezanzadeh,M. Shahidzadeh,F. Noroozi 한국공업화학회 2013 Journal of Industrial and Engineering Chemistry Vol.19 No.6
Chain extenders including diethanol amine (DEA) and 2-cyano-N,N-bis-hydroxyethyl acetamide (CNBA)were utilized to enhance the adhesion and mechanical properties of a polyurethane (PU) adhesive. The adhesion and mechanical properties of the adhesives were studied by peel test, tensile test and dynamic thermal analysis (DMTA) respectively. Results revealed that both chain extenders (DEA and CNBA)increased peel test modulus. The cross-linking density and toughness of the adhesive were significantly increased using chain extenders. Results showed that chain extender without side chain (DEA) could improve the adhesion and mechanical properties of the adhesive greater than chain extender with aliphatic side group (CNBA).