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      • KCI등재

        Synthesis, physical, optical and radiation shielding properties of Barium-Bismuth Oxide Borate-A novel nanomaterial

        Chandrika B.M.,Manjunatha Holaly Chandrashekara Shastry,Sridhar K.N.,Ambika M.R.,Seenappa L.,Manjunatha S.,Munirathnam R.,Lourduraj A.J. Clement 한국원자력학회 2023 Nuclear Engineering and Technology Vol.55 No.5

        Barium Bismuth Oxide Borate (BBOB) has been synthesized for the first time using solution combustion technique. SEM analysis reveal flower shape of the nanoparticles. The formation of the nanoparticles has been confirmed through XRD & FTIR studies which gives the physical and chemical structure of the novel material. The UV light absorption is observed in the range 200e300 nm. The present study highlights the radiation shielding ability of BBOB for different radiations like X/Gamma rays, Bremsstrauhlung and neutrons. The gamma shielding efficiency is comparable to that of lead in lower energy range and lesser than lead in the higher energy range. The bremsstrauhlung exposure constant is comparably larger for BBOB NPs than that of concrete and steel however it is lesser than that of lead. The beauty of BBOB nanoparticles lies in, high absorption of radiations and low emission of secondary radiations when compared to lead. In addition, the neutron shielding parameters like scattering length, absorption and scattering cross sections of BBOB are found to be much better than lead, steel and concrete. Thus, BBOB nanoparticles are highly efficient in absorbing X/Gamma rays, neutrons and bremsstrauhlung radiations

      • KCI등재

        Green synthesis of Lead–Nickel–Copper nanocomposite for radiation shielding

        Chandrika B.M.,Manjunatha Holaly Chandrashekara Shastry,Munirathnam R.,Sridhar K.N.,Seenappa L.,Manjunatha S.,Lourduraj A.J. Clement 한국원자력학회 2023 Nuclear Engineering and Technology Vol.55 No.12

        For the first time Pb, Ni, and Cu nanocomposites were synthesized by versatile solution combustion synthesis using extract as a reducing agent, to study the potential applications in X-ray/gamma, neutron, and Bremsstrahlung shielding. The synthesized Lead–Nickel–Copper (LNC) nanocomposites were characterized by PXRD, SEM, UV–VIS, and FTIR for the confirmation of successful synthesis. PXRD analysis confirmed the formation of multiphase LNC NCs and the Scherrer equation and the W-H plot gave the average crystal sizes of 19 nm and 17 nm. Surface morphology using SEM and EDX confirmed the presence of LNC NCs. Strong absorption peaks were analyzed by UV visible spectroscopy and the direct energy gap is found to be 3.083 eV. Functional groups present in the LNC NCs were analyzed by FTIR spectroscopy. X-ray/gamma radiation shielding properties were measured using NaI(Tl) detector coupled with MCA. It is found to be very close to Pb. Neutron shielding parameters were compared with traditional shielding materials and found LNC NCs are better than lead and concrete. Secondary radiation shielding known as Bremsstrahlung shielding characteristics also studied and found that LNC NCs are best in secondary radiation shielding. Hence LNC NCs find shielding applications in ionizing radiation such as X-ray/gamma and neutron radiation

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