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        Self‑Supported Phosphorus‑Doped Vertically Aligned Graphene Arrays Integrated with FeCoNiP Nanoparticles as Bifunctional Electrocatalysts for Water‑Splitting Over a Wide pH Range

        Zujin Yang,Firdoz Shaik,Keming Liang,Kaiming Guo,Xiaolin Ren,Bin Jiang 대한금속·재료학회 2021 ELECTRONIC MATERIALS LETTERS Vol.17 No.1

        Self-supported non-noble metal based bifunctional electrocatalysts with high catalytic activity and long-term stability in awide pH range are highly essential for the production of hydrogen and oxygen, remains a great challenge. Herein, a bifunctional electrocatalyst is synthesized via electroless plating of FeCoNiP nanoparticles on self-supported phosphorus-dopedvertically aligned graphene arrays (FeCoNiP/P-VG). FeCoNiP/P-VG exhibits an exceptionally high catalytic activity forhydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in a wide pH range, with an overpotential of 81and 141 mV for HER, and 240 and 409 mV for OER, in 1.0 M KOH and 0.5 M H2SO4 respectively, at current density of10 mA. It also performs quite low Tafel slope value of 40 mV·dec−1 for HER and 69 mV·dec−1 for OER in 1.0 M KOH. More importantly, it shows prominent stability in acidic and alkaline electrolytes. This study may open a new avenue for thedesign and fabrication of self-supported bifunctional electrocatalysts for water splitting.

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        Transfer zones within the Longmen Mountains thrust belt, SW China

        Wenzheng Jin,Liangjie Tang,Keming Yang,Guimei Wan,Zhizhou Lü,Yixin Yu 한국지질과학협의회 2009 Geosciences Journal Vol.13 No.1

        The Longmen Mountains thrust belt contains complex structures resulting from multi-phase tectonic movements. Field investigations and interpretations of seismic profiles reveal two important transfer zones in the thrust belt: the Anxian and Guanxian transfer zones. Many thrust and strike-slip faults are found in the shallow part of the transfer zones, and duplexes and detachment structures in the deep part. The Anxian transfer zone is located between the Jiaoziding and Jiudingshan nappes, consisting mainly of the Lower Triassic Feixianguan Formation (T1 f ) and Jianglingjiang Formation (T1 j), and Middle Triassic Leikoupo Formation (T2l). The Guanxian transfer zone is located between the Baoxing and Jiudingshan nappes, consisting mainly of Devonian, Carboniferous, Triassic, Jurassic, and Presinian rocks. This zone contains many thrust faults, strike-slip faults, and duplexes in its deeper part (where early structures have been almost completely overprinted), and many klippens are found at the surface.

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