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        Magnetic and Thermoelectric Properties of the Mn1−XNiXS Solid Solutions

        Genady Makovetskii,Olga Demidenko,Anatoly Galyas,Kazimir Yanushkevich,Sergey Aplesnin,Oxana Romanova,Ludmila Ryabinkina 한국물리학회 2013 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.62 No.12

        The new sulphide Mn1−XNiXS (0 < X ≤ 0.1) solid solutions are synthesized. The structural,magnetic, electric and thermoelectric properties of the obtained materials have been studied. TheX-ray diffraction analysis has shown that the synthesized Mn1−XNiXS samples have a NaCl-typeFCC lattice. The Mn1−XNiXS samples are antiferromagnets with the Neel temperature (TN = 180K for X = 0.05 and TN = 200 K for X = 0.1). The temperature dependence of magnetization isdescribed by the Curie-Weiss law at T > TN. The conductivity type change from the hole to theelectronic at X > 0.05 is revealed on the basis of the thermoelectric power measurements. Theresistivity and thermopower behaviors are explained in terms of the impurity subband formationinto MnS electron excitation gap.The new sulphide Mn1−XNiXS (0 < X ≤ 0.1) solid solutions are synthesized. The structural,magnetic, electric and thermoelectric properties of the obtained materials have been studied. TheX-ray diffraction analysis has shown that the synthesized Mn1−XNiXS samples have a NaCl-typeFCC lattice. The Mn1−XNiXS samples are antiferromagnets with the Neel temperature (TN = 180K for X = 0.05 and TN = 200 K for X = 0.1). The temperature dependence of magnetization isdescribed by the Curie-Weiss law at T > TN. The conductivity type change from the hole to theelectronic at X > 0.05 is revealed on the basis of the thermoelectric power measurements. Theresistivity and thermopower behaviors are explained in terms of the impurity subband formationinto MnS electron excitation gap.

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