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Iwahashi, Takashi,Sakai, Yasunari,Kanai, Kaname,Kim, Doseok,Ouchi, Yukio Royal Society of Chemistry 2010 Physical chemistry chemical physics Vol.12 No.40
<P>We demonstrate for the first time the formation of a non-polar alkyl-chain dividing layer between a room-temperature ionic liquid (RTIL) and an <I>n</I>-alcohol. This newly described non-polar interfacial layer, which should be more hydrophobic than both RTIL and alcohol phases, might find applications in liquid/liquid reaction systems, or serve as a soft nano-functional space.</P> <P>Graphic Abstract</P><P>A non-polar alkyl-chain dividing layer is found to exist between butanol and the room-temperature ionic liquid 1-butyl-3-methyl-imidazolium hexafluorophosphate. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c0cp00520g'> </P>
Ito, Eisuke,Hara, Masahiko,Kanai, Kaname,Ouchi, Yukio,Seki, Kazuhiko,Noh, Jaegeun Korean Chemical Society 2009 Bulletin of the Korean Chemical Society Vol.30 No.8
Surface structure and molecular orientation of self-assembled monolayers (SAMs) formed by the spontaneous adsorption of tetrahydrothiophene (THT) and thiophene (TP) on Au(111) were investigated by means of scanning tunneling microscopy (STM) and carbon K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. STM imaging revealed that THT SAMs have a commensurate (3 ${\times}\;2\sqrt[]{3}$) structure containing structural defects in ordered domains, whereas TP SAMs are composed of randomly adsorbed domains and paired molecular row domains that can be described as an incommensurate packing structure. The NEXAFS spectroscopy study showed that the average tilt angle of the aliphatic THT ring and $\pi$-conjugated TP ring in the SAMs were calculated to be about $30^o\;and\;40^o$, respectively, from the surface normal. It was also observed that the $\pi$* transition peak in the NEXAFS spectrum of the TP SAMs is very weak, suggesting that a strong interaction between $\pi$-electrons and the Au surface arises during the self-assembly of TP molecules. In this study, we have clearly demonstrated that the surface structure and adsorption orientation of organic SAMs on Au(111) are strongly influenced by whether the cyclic ring is saturated or unsaturated.
Eisuke Ito,Masahiko Hara,Kaname Kanai,Yukio Ouchi,Kazuhiko Seki,노재근 대한화학회 2009 Bulletin of the Korean Chemical Society Vol.30 No.8
Surface structure and molecular orientation of self-assembled monolayers (SAMs) formed by the spontaneous adsorption of tetrahydrothiophene (THT) and thiophene (TP) on Au(111) were investigated by means of scanning tunneling microscopy (STM) and carbon K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. STM imaging revealed that THT SAMs have a commensurate (3 × 2√3) structure containing structural defects in ordered domains, whereas TP SAMs are composed of randomly adsorbed domains and paired molecular row domains that can be described as an incommensurate packing structure. The NEXAFS spectroscopy study showed that the average tilt angle of the aliphatic THT ring and π-conjugated TP ring in the SAMs were calculated to be about 30o and 40o, respectively, from the surface normal. It was also observed that the π* transition peak in the NEXAFS spectrum of the TP SAMs is very weak, suggesting that a strong interaction between π-electrons and the Au surface arises during the self-assembly of TP molecules. In this study, we have clearly demonstrated that the surface structure and adsorption orientation of organic SAMs on Au(111) are strongly influenced by whether the cyclic ring is saturated or unsaturated.