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Study on fractal model of activated carbon for pore formation
Wang Junzhe,Zhou Anning,Liu Guoyang,Song Zongxing,Ma Chao,Wang Dan 한국탄소학회 2022 Carbon Letters Vol.32 No.3
In view of the activated carbon pore-forming mechanism, the fractal hypothesis of pore interior growth was proposed by optimizing the structure of Sierpinski sponge. Based on the hypothesis and the definition of fractal dimension, the function relationship between the reaction degree, reaction step length, specific surface area and pore volume was deduced, and the pore fractal growth model of activated carbon activation process was established. Semi-coke, apple charcoal and lychee charcoal were used to prepare activated carbon. The pore size distributions of the activated carbons are in accordance with the fractal growth hypothesis. Further, the reaction degree and reaction step length can be determined by the experimental data of pore and surface structure, which verified the feasibility of the pore fractal growth model.
Jiansheng Shen,Junzhe Liu,Yidong Xu,Kanghao Jia,Fangyu Wu,Wei Chen,Dayong Zhu 대한토목학회 2021 KSCE JOURNAL OF CIVIL ENGINEERING Vol.25 No.9
To study the corrosion cracking process of reinforced concrete under the combined effects of chloride and fatigue loading, the constan-current and dry-wet cycle accelerated corrosion method was used to corrosion the specimens under different stress levels for different time. The quality loss of reinforcement, the composition of corrosion products and the cracking of concrete are analyzed from the macro, micro and micro scales, and to obtain the spatial distribution as well as microscopic characteristics of corrosion products of the reinforcement bar under coupling conditions. Additionally, a model of steel rust cracking under the coupled action of chloride and fatigue loading is established. The results show that: under the same corrosion time, the concrete cracking and steel corrosion degree become more serious with the increase of stress level. The greater the stress level, the earlier corrosion occurs and the more corrosion products are, Moreover, due to the fatigue load, the concrete on the upper side of the steel bar has rust expansion cracks earlier than the lower side.