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Jun Hu,Can Tao,Aining Yuan,Junjie Bao,Qin Cheng,Gewen Xu,Yiping Huang 한국고분자학회 2019 폴리머 Vol.43 No.2
Series of waterborne polyurethanes (WPUs) containing poly(tetra methylene glycol) (PTMG), 4,4-dicyclohexylmethane diisocyanate (HMDI), 2,2-dimethylolpropionic acid (DMPA), 2,2,4-trimethyl-1,3-pentanediol (TMPD), isosorbide (ISO) and ethylenediamine (EDA) were synthesized. The effects of ISO on the structure and properties of WPUs were studied by gel permeation chromatography (GPC), Fourier-transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), dynamic mechanical analyzer (DMTA), X-ray diffraction (XRD), thermogravimetry (TG), mechanical test, chemical resistance and hardness test. The deconvolution analysis of FTIR of WPUs revealed that the hydrogen bond interaction in the WPUs increased with the increase of ISO content. Furthermore, the degree of microphase separation was increased with the increase of hydrogen bond interaction, which was confirmed by DSC, XRD and DMTA test. The results demonstrated that the addition of ISO can increase the hydrogen bond interaction between the hard and hard segments in WPUs, which improved the mechanical properties of the WPU films. The highest tensile strength was obtained of 59.67 MPa when the content of isosorbide was 10.35 wt%. Moreover, the ISO was helpful to improve the chemical resistance and hardness of the coatings by the comprehensive performance analysis.
Xixi Han,Can Tao,Zhiqian Xie,Junjie Bao,Yiping Huang,Gewen Xu 한국고분자학회 2017 폴리머 Vol.41 No.3
Cationic waterborne polyurethane fluorescent material based on 4"-p-N,N-bis(2-hydroxyethyl)benzyl-3,3":6",2""-terpyridine (TPPDA-CWPU) was synthesized. The structure was characterized by FTIR and UV-vis spectroscopy. The content of TPPDA in the fluorescent polyurethane was 6.3×10<SUP>-4</SUP> mg/mg and the grafting ratio was 33.87%. The number-averaged and weight-average molecular weights of TPPDA-CWPU were about 16060 and 27131 g·mol<SUP>-1</SUP>, respectively. The maximum absorption wavelength of TPPDA-CWPU was blue shifted ca. 6 nm compared to TPPDA. TPPDACWPU showed different fluorescence properties under different solid content. Compared with 20% solid content, the fluorescence intensity of 1% solid content increased by ten times. The quantum yield of TPPDA-CWPU was 0.3, which was four times higher than that of TPPDA. Moreover, TPPDA-CWPU was sensitive to acidic condition and there was the phenomenon of fluorescence quenching in the case of strong acidic conditions. It is believed that more applications will be possible in the pH-responsive polymer.