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- 저자 : Jordi Llorca (검색결과 4 건)
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Evolution pathway of CZTSe nanoparticles synthesized by microwave-assisted chemical synthesis
Reyes, Odin,Sanchez, Monica F.,Pal, Mou,Llorca, Jordi,Sebastian, P.J. Techno-Press 2017 Advances in nano research Vol.5 No.3
In this study we present the reaction mechanism of $Cu_2ZnSnSe_4$ (CZTSe) nanoparticles synthesized by microwave-assisted chemical synthesis. We performed reactions every 10 minutes in order to identify different phases during quaternary CZTSe formation. The powder samples were analyzed by x-ray diffraction (XRD), Raman spectroscopy, energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The results showed that in the first minutes copper phases are predominant, then copper and tin secondary phases react to form ternary phase. The quaternary phase is formed at 50 minutes while ternary and secondary phases are consumed. At 60 minutes pure quaternary CZTSe phase is present. After 60 minutes the quaternary phase decomposes in the previous ternary and secondary phases, which indicates that 60 minutes is ideal reaction time. The EDS analysis of pure quaternary nanocrystals (CZTSe) showed stoichiometric relations similar to the reported research in the literature, which falls in the range of Cu/(Zn+Sn): 0.8-1.0, Zn/Sn: 1.0-1.20. In conclusion, the evolution pathway of CZTSe synthesized by this novel method is similar to other synthesis methods reported before. Nanoparticles synthesized in this study present desirable properties in order to use them in solar cell and photoelectrochemical cell applications.
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Molybdenum release from high burnup spent nuclear fuel at alkaline and hyperalkaline pH
García-Gómez Sonia,Giménez Javier,Casas Ignasi,Llorca Jordi,De Pablo Joan,Martínez-Torrents Albert,Clarens Frederic,Kokinda Jakub,Iglesias Luis,Serrano-Purroy Daniel 한국원자력학회 2024 Nuclear Engineering and Technology Vol.56 No.1
This work presents experimental data and modelling of the release of Mo from high-burnup spent nuclear fuel (63 MWd/kgU) at two different pH values, 8.4 and 13.2 in air. The release of Mo from SF to the solution is around two orders of magnitude higher at pH = 13.2 than at pH = 8.4. The high Mo release at high pH would indicate that Mo would not be congruently released with uranium and would have an important contribution to the Instant Release Fraction, with a value of 5.3%. Parallel experiments with pure non irradiated Mo(s) and XPS determinations indicated that the faster dissolution at pH = 13.2 could be the consequence of the higher releases from metallic Mo in the fuel through a surface complexation mechanism promoted by the OH and the oxidation of the metal to Mo(VI) via the formation of intermediate Mo(IV) and Mo(V) species.
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Gerardo Gómez Millán,Sanna Hellsten,Alistair W.T. King,Juha-Pekka Pokki,Jordi Llorca,Herbert Sixta 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.72 No.-
Furfural (FUR) was produced from xylose using a biphasic batch reaction system. Water-immiscibleorganic solvents such as isophorone, 2-methyltetrahydrofuran (2-MTHF) and cyclopentyl methyl ether(CPME) were used to promptly extract FUR from the aqueous phase in order to avoid the degradation tohumins as largely as possible. The effect of time, temperature, organic solvent and organic-to-aqueousratio on xylose conversion and FUR yield were investigated in auto-catalyzed conditions. Experiments atthree temperatures (170, 190 and 210 C) were carried out in a stirred microwave-assisted batch reactor,which established the optimal conditions for achieving the highest FUR yield. The maximum FUR yieldsfrom xylose were 78 mol% when using CPME, 48 mol% using isophorone and 71 mol% in the case of 2-MTHF at an aqueous to organic phase ratio of 1:1 (v/v). Birch hydrolysate was also used to show the highfurfural yield that can be obtained in the biphasic system under optimized conditions. The present studysuggests that CPME can be used as a green and efficient extraction solvent for the conversion of xyloseinto furfural without salt addition.
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Carbonaceous catalysts from orange pulp for limonene oxidation
Wróblewska Agnieszka,Serafin Jarosław,Gawarecka Alicja,Miądlicki Piotr,Urbaś Karolina,Koren Zvi C.,Llorca Jordi,Michalkiewicz Beata 한국탄소학회 2020 Carbon Letters Vol.30 No.2
The possibility of orange pulp utilization for nanoporous carbons production was investigated. Moreover, processing the obtained materials as limonene oxidation catalysts was studied as well. Limonene was separated from orange pulp obtained from fragmented orange peels—the waste from industrial fruits processing—by means of simple distillation. After the sepa�ration of limonene from the biomass, the dried orange pulp was converted to three types of nanoporous carbon catalysts: without activating agent, with NaOH, and with KOH. The catalysts were characterized by XRD, SEM, EDX, AFM, and sorption of N2 methods. The activities of the obtained catalysts were tested in the oxidation of limonene to perillyl alcohol (the main product), carveol, carvone, and 1,2-epoxylimonene and its diol. In the oxidation processes, hydrogen peroxide was used as the oxidizing agent. This work has shown for the frst time that nanoporous carbons obtained from orange pulp waste, after separation of limonene, are active catalysts for limonene oxidation to industrially important value-added products.
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