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Selective Laser Pyrolytic Micropatterning of Stretched Elastomeric Polymer Surfaces
Eunseung Hwang,Younggeun Lee,Jaemook Lim,Youngchan Kim,Weihao Qu,Koungjun Min,이원철,홍석준 한국정밀공학회 2021 International Journal of Precision Engineering and Vol.8 No.3
The patterning of surface structures is a critical step for interfacial engineering applications that are based on soft lithography, casting, or imprinting techniques in general. However, photolithography and mold/die fabrication processes are expensive and time-consuming. To solve this problem, we developed a novel laser-based process that exploits the high stretchability of a polymer. In this study, continuous-wave laser-induced pyrolysis was conducted on a pre-stretched Ecoflex polymer substrate to obtain a controllable hydrophobic surface with functional structures at the micro/nanoscale, which were constructed via the facile removal of pyrolytic byproducts. Under the optimum strain rate and laser parameters, periodic wrinkle generation and a proportional channel pitch reduction were observed, which provided hierarchical micro/nanostructures and enlarged the air gaps between the target droplet and the hydrophobic structures. The processed surface exhibited improved hydrophobic properties (WCA ~ 135°) compared with a flat Ecoflex polymer surface (WCA ~ 105°). Thus, a facile manufacturing method for stretchable polymer substrates with hydrophobic patterned surfaces is proposed.