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        Volcanic-hypabyssal rock geochemistry of a subduction-related marginal basin ophiolite: Southeast Bohol Ophiolite-Cansiwang M?ange Complex, Central Philippines

        D.V. Faustino,G.P. Yumul, Jr.,C.B. Dimalanta,J.V. de Jesus,M-F. Zhou,J.C. Aitchison,R.A. Tamayo, Jr. 한국지질과학협의회 2006 Geosciences Journal Vol.10 No.3

        The Early Cretaceous Southeast Bohol Ophiolite-Cansiwang Mlange Complex and the Alicia Schist form thebasement of southeastern Bohol Island in central Philippines.New geochemical data show that four discrete groups consti-tute the volcanic and associated hypabyssal rocks of the ophi-olite-mlange complex: boninitic rocks (BON), enriched andnormal mid-ocean ridge basalt-like rocks (E-MORB; N-MORB) and high-magnesian andesites (HMA). Of these fourgroups, the BON are the most depleted in REEs and with themost pronounced negative Nb anomalies. Both MORB-liketypes exhibit subduction-zone influence as reflected in theirslight negative Nb anomalies. Characteristically with flat andLREE-depleted patterns, the HMA samples apear to mimicN-MORB patterns but with lower REE concentrations. Thisgeochemical diversity is best explained by a suprasubductionzone environment of formation as is also evident from field geo-believed to have ben concurrent with the ophiolite’s emplace-ment by subduction-accretion along a forearc margin. This tec-tonic boundary was later jammed into inactivity with the entryof the Alicia Schist that most likely was an oceanic bathymetrichigh. The intercalation of both tufaceous materials and pelagicchert with the pillow basalts are consistent with a marginalbasin tectonic setting.

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        Rietveld refinement, microstructure, conductivity and impedance properties of Ba[Zr_0.25Ti_0.75]O_3 ceramic

        T. Badapanda,V. Senthil,S.K. Rout,L.S. Cavalcante,A.Z. Simões,T. P. Sinha,S. Panigrahi,M.M. de Jesus,E. Longo,J.A. Varela 한국물리학회 2011 Current Applied Physics Vol.11 No.6

        In this work, we report the Rietveld refinement, microstructure, conductivity and impedance properties of Ba[Zr_0.25Ti_0.75]O_3 ceramic synthesized by solid state reaction. This ceramic was characterized by X-ray diffraction, Rietveld refinement, scanning electron microscopy and energy dispersive X-ray spectrometry. Impedance spectroscopy analyses reveals a non-Debye relaxation phenomenon being its relaxation frequency moving toward to positive side with increase of temperature. A significant shift in impedance loss peaks toward higher frequency side indicates conduction in material and favoring the long range motion of mobile charge carriers. The frequency dependent ac conductivity at different temperatures indicates that the conduction process is thermally activated. The variation of dc conductivity exhibited a negative temperature coefficient of resistance behavior. The ac conductivity data are used to evaluate the density of states at Fermi level and activation energy of this ceramic. The dc electrical and thermal conductivities of grain and grain boundary have been discussed.

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