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B40 fullerene: An efficient material for CO2 capture, storage and separation
Huilong Dong,Bin Lin,Keith Gilmore,Tingjun Hou,Shuit-Tong Lee,Youyong Li 한국물리학회 2015 Current Applied Physics Vol.15 No.9
Novel nanomaterials are promising for capture, storage and separation of CO2. By density functional calculations, we find that the newly discovered B40 fullerene is a suitable candidate. CO2 forms stable chemisorptions with B40 on specific sites, which is validated by the high adsorption energy, large charge transfer, and kinetic feasibility for B40(CO2) complexes. Due to the strong chemisorption, B40 shows high adsorption capacity for CO2 (up to 13.87 mmol/g). In addition, B40 shows good selectivity for CO2 and is efficient in separating it from gas mixtures like CO2/N2, CO2/H2, and CO2/CH4.
Zhaoran Wang,Huilong Dong,Xiaohui Yu,Yujin Ji,Tingjun Hou,Youyong Li 한국물리학회 2017 Current Applied Physics Vol.17 No.12
Porous monolayer materials have been proven potential for gas separation and purification, because of their natural pathways of controllable sizes and well-ordered distribution. In this work, a novel material, two-dimensional (2D) porous polyphthalocyanine (PPc) is investigated by density functional theory (DFT) simulations for separating NH3 from H2 and N2 during ammonia synthesis process. Based on the calculated diffusion barriers through transition state search, we demonstrate that 2D PPc is able to offer high selectivity (107) of (H2, N2)/NH3 at room temperature. Further molecular dynamics (MD) simulation also indicates that the 2D PPc can effectively separate NH3 from H2 and N2. Thus the 2D PPc is promising for the practical applications of synthetic ammonia process.
Hydrodynamic Characteristics of Cylindrical Spiral Grooves for Pump Annular Seals
Yuanzheng Wu,Huilong Chen,Benjamin Bernard Uzoejinwa,Binjuan Zhao,Dong Xu 한국유체기계학회 2020 International journal of fluid machinery and syste Vol.13 No.2
The hydrodynamic characteristics of pump annular seals are closely related to the internal flow characteristics and the pump operation stability. Previous studies of annular seals texture focus on damp rather than stiffness. Here a new spiral groove texture on cylindrical surface of annular seals is proposed. Based on the N-S equations, CFD method considering cavitation is used to simulate the internal flow of the spiral groove annular seals. Eccentricity is ensured by the moving mesh technology. The flow characteristics are studied, and comparatively analyzed with that of the smooth annular seals. Results show that: the spiral groove can generate the dynamic pressure effect and the pumping effect. Obvious changes in the pressure field appear. With eccentricity, the spiral groove can respectively enhance the stiffness, reset force and reduce the offset angle, which indicates that the spiral groove is helpful to acquire better rotor concentricity. The spiral groove also reduces the leakage and has little impact on the frictional torque. The above results demonstrate that the spiral groove is beneficial to improve the hydrodynamic characteristics of the annular seals and the concentricity of the rotor, which also reduces friction and wear.
Flexible Nanoporous WO<sub>3–<i>x</i></sub> Nonvolatile Memory Device
Ji, Yongsung,Yang, Yang,Lee, Seoung-Ki,Ruan, Gedeng,Kim, Tae-Wook,Fei, Huilong,Lee, Seung-Hoon,Kim, Dong-Yu,Yoon, Jongwon,Tour, James M. American Chemical Society 2016 ACS NANO Vol.10 No.8
<P>Flexible resistive random access memory (RRAM) devices have attracted great interest for future nonvolatile memories. However, making active layer films at high temperature can be a hindrance to RRAM device fabrication on flexible substrates. Here, we introduced a flexible nanoporous (NP) WO3-x RRAM device using anodic treatment in a room-temperature process. The flexible NP WO3-x RRAM device showed bipolar switching characteristics and a high I-ON/IOFF ratio of similar to 10(5). The device also showed stable retention time over 5 X 10(5) s, outstanding cell-to-cell uniformity, and bending endurance over 10(3) cycles when maximum bending conditions.</P>